(η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium

Base Information

• Chemical Name: (η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium
• CAS No.: 85320-11-2
• Molecular Formula: C₂₂H₁₉Cl₂PTi
• Molecular Weight: 433.153
• Mol file: 85320-11-2.mol

Synonyms:(η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium

Chemical Property of (η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium

There total 1 articles about (η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

cyclopentadienyl titanium(IV) trichloride (1270-98-0) + lithium diphenylphosphinocyclopentadienyl (83272-80-4) → (η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium (85320-11-2)

Guidance literature:

In tetrahydrofuran; byproducts: LiCl; Li-compd. in THF was added to thf soln. of CpTiCl3 in 1:1 molar ratio, mixt. was stirred for 4 h at room temp; solvent was removed in vac., residue was extd. with CH2Cl2, soln. was filtered through Celite, hexane was added, soln. was filtered, cooled at -20 °C overnight, residue was dried in vac., ele. anal.;

DOI:10.1016/S0022-328X(00)00219-9

Reference yield: 85.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + (η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium (85320-11-2) → (η(6)-p-cymene)[(η(5)-C5H5)(μ-η(5):η(1)-Ph2PC5H4)TiCl2]RuCl2

Guidance literature:

In benzene; under Ar, phosphine:Ru-compd. molar ratio was 2:1, stirring for 4 h at room temp.; ppt. was filtered and dried in vac., elem. anal.;

DOI:10.1016/S0022-328X(00)00219-9

Reference yield: 83.0%

(η5-cyclopentadienyl)[η5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium (85320-11-2) + copper(l) chloride → [CpTiCl2Cp-PPh2]2CuCl

Guidance literature:

In benzene; (Ar); C6H6 added to a mixt. of Ti and Cu compds., stirred at room temp.; filtered, dried (vac.), recrystd. (CH2Cl2/hexane); elem. anal.;

DOI:10.1021/ic8023869

upstream raw materials:

cyclopentadienyl titanium(IV) trichloride

lithium diphenylphosphinocyclopentadienyl

Downstream raw materials:

(η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dicarbonyltitanium

(η-5-cyclopentadienyl)dicarbony((η-5-cyclopentadienyl)[η-5-(diphenylphosphino)cyclopentadienyl]dichlorotitanium-P)manganese