(2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate

Base Information

• Chemical Name: (2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate
• CAS No.: 107686-57-7
• Molecular Formula: C₂₄H₂₈O₂
• Molecular Weight: 348.485
• Mol file: 107686-57-7.mol

Synonyms:(2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate

Chemical Property of (2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate

There total 2 articles about (2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

3-(2-methyl-1-propenyl)-2,2-dimethylcyclopropanecarbonyl chloride (4489-12-7,4489-14-9,26770-95-6,28684-92-6,34909-52-9,51348-74-4,53955-46-7,56650-12-5,14297-81-5) + (2-methyl-[1,1′-biphenyl]-3-yl)methanol (76350-90-8) → (2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate (107686-57-7)

Guidance literature:

In pyridine; diethyl ether; for 3h; Ambient temperature;

DOI:10.1246/bcsj.60.4385

Reference yield:

→ (2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate (107686-57-7)

Guidance literature:

Reference yield:

(2-methyl-3-phenylphenyl)methyl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate (107686-57-7) → (1R,3S)-3-((Z)-2-Chloro-3,3,3-trifluoro-propenyl)-2,2-dimethyl-cyclopropanecarboxylic acid 2-methyl-biphenyl-3-ylmethyl ester (82657-04-3,83322-02-5,87648-90-6,87680-56-6,99267-18-2,107538-31-8,107538-32-9,107538-33-0,107538-34-1,131100-77-1,92880-79-0,107497-60-9)

Guidance literature:

Multi-step reaction with 4 steps

1: O₃

2: 86 percent / Zn / dimethylformamide

3: 100 percent / pyridine

4: 95 percent / Zn / dimethylformamide

With pyridine; ozone; zinc; In N,N-dimethyl-formamide;

DOI:10.1016/S0040-4039(00)84469-X

upstream raw materials:

3-(2-methyl-1-propenyl)-2,2-dimethylcyclopropanecarbonyl chloride

(2-methyl-[1,1′-biphenyl]-3-yl)methanol

Downstream raw materials:

(2-methyl[1,1'-biphenyl]-3-yl)methyl cis,trans-2,2-dimethyl-3-formylcyclopropanecarboxylate

(1R,3S)-3-((Z)-2-Chloro-3,3,3-trifluoro-propenyl)-2,2-dimethyl-cyclopropanecarboxylic acid 2-methyl-biphenyl-3-ylmethyl ester

(2-methyl-3-phenylphenyl)methyl (1RS,3SR)-3-(1-acetoxy-2,2-dichloro-3,3,3-trifluoropropyl)-2,2-dimethylcyclopropanecarboxylate

(2-methyl-3-phenylphenyl)methyl (1RS,3SR)-3-(2,2-dichloro-3,3,3-trifluoro-1-hydroxypropyl)-2,2-dimethylcyclopropanecarboxylate