Technology Process of C38H52O6Si
There total 3 articles about C38H52O6Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C38H50O6Si;
With
sodium tetrahydroborate; diethyl methoxy borane;
In
tetrahydrofuran; methanol;
at -78 ℃;
In
methanol;
Further stages.;
DOI:10.1021/ol070517g
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 70 percent / oxygen; copper(II) acetate monohydrate / PdCl2 / N,N-dimethyl-acetamide; H2O / 12 h
2.1: ethyldiisopropylamine; dibutylboron triflate / CH2Cl2; diethyl ether / -78 - -50 °C
2.2: CH2Cl2; diethyl ether / 6 h / -78 - -50 °C
2.3: 72 percent / aq. H2O2 / various solvents / pH 7
3.1: diethyl(methoxy)borane; NaBH4 / tetrahydrofuran; methanol / -78 °C
3.2: 85 percent / methanol
With
sodium tetrahydroborate; di-n-butylboryl trifluoromethanesulfonate; diethyl methoxy borane; oxygen; copper diacetate; N-ethyl-N,N-diisopropylamine;
palladium dichloride;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl acetamide; water;
1.1: Wacker reaction / 2.2: Evans aldol reaction;
DOI:10.1021/ol070517g
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: ethyldiisopropylamine; dibutylboron triflate / CH2Cl2; diethyl ether / -78 - -50 °C
1.2: CH2Cl2; diethyl ether / 6 h / -78 - -50 °C
1.3: 72 percent / aq. H2O2 / various solvents / pH 7
2.1: diethyl(methoxy)borane; NaBH4 / tetrahydrofuran; methanol / -78 °C
2.2: 85 percent / methanol
With
sodium tetrahydroborate; di-n-butylboryl trifluoromethanesulfonate; diethyl methoxy borane; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane;
1.2: Evans aldol reaction;
DOI:10.1021/ol070517g