Ethanone, 1-(2-methylphenyl)-2-[(methylsulfonyl)oxy]- (9CI)

Base Information

• Chemical Name: Ethanone, 1-(2-methylphenyl)-2-[(methylsulfonyl)oxy]- (9CI)
• CAS No.: 799804-23-2
• Molecular Formula: C10H12 O4 S
• Molecular Weight: 228.269
• Mol file: 799804-23-2.mol

Synonyms:Ethanone, 1-(2-methylphenyl)-2-[(methylsulfonyl)oxy]- (9CI)

Chemical Property of Ethanone, 1-(2-methylphenyl)-2-[(methylsulfonyl)oxy]- (9CI)

Chemical Property:

• PSA: 68.82000
• LogP: 2.23470

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethanone, 1-(2-methylphenyl)-2-[(methylsulfonyl)oxy]- (9CI)

There total 2 articles about Ethanone, 1-(2-methylphenyl)-2-[(methylsulfonyl)oxy]- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

(mesyloxyhydroxyiodo)benzene (105551-42-6) + 2-Methylacetophenone (577-16-2,122382-54-1) → 2-mesyloxy-1-(2-methylphenyl)-1-ethanone (799804-23-2)

Guidance literature:

DOI:10.1021/jo040173x

Reference yield: 82.0%

methanesulfonic acid (75-75-2,98527-29-8) + 1-ethynyl-2-methylbenzene (766-47-2) + acetic acid (64-19-7,77671-22-8) → α-acetoxy-o-methylacetophenone (98750-17-5) + 2-mesyloxy-1-(2-methylphenyl)-1-ethanone (799804-23-2)

Guidance literature:

With 8-methylquinoline 1-oxide; [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I); at 20 ℃; for 8h;

DOI:10.1055/s-0033-1338513

Reference yield: 42.0%

2-mesyloxy-1-(2-methylphenyl)-1-ethanone (799804-23-2) → inden-1-one (83-33-0)

Guidance literature:

With 1-methyl-1H-imidazole; In dichloromethane; Irradiation;

DOI:10.1021/jo040173x

upstream raw materials:

(mesyloxyhydroxyiodo)benzene

2-Methylacetophenone

methanesulfonic acid

1-ethynyl-2-methylbenzene

Downstream raw materials:

1-[2-(methoxymethyl)phenyl]-1-ethanone

inden-1-one