(1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-(1-aminoethyl)-4-bromobenzene

Base Information

Chemical Name:(1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-(1-aminoethyl)-4-bromobenzene
CAS No.:1005795-38-9
Molecular Formula:C₂₂H₂₃BrN₂O₃S₂
Molecular Weight:507.472
Hs Code.:

Synonyms:(1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-(1-aminoethyl)-4-bromobenzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-(1-aminoethyl)-4-bromobenzene

Chemical Property:

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Technology Process of (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-(1-aminoethyl)-4-bromobenzene

There total 6 articles about (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-(1-aminoethyl)-4-bromobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 816444-61-8
N-[(1S)-amino(4-tolyl)oxido-λ⁴-sulfanylidene]tosylamide

: 1585-07-5
1-bromo-4-ethylbenzene

: 1005795-38-9
(1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-(1-aminoethyl)-4-bromobenzene

Guidance literature:: With 4 A molecular sieve; (S)-N-1,8-naphthoylalanine dirhodium complex; In methanol; 1,1,2,2-tetrachloroethane; at -35 ℃; for 72h;
DOI:10.1021/ja076519d

Reference yield:

: 816444-61-8
N-[(1S)-amino(4-tolyl)oxido-λ⁴-sulfanylidene]tosylamide

: 1585-07-5
1-bromo-4-ethylbenzene

: 100-41-4,27536-89-6
ethylbenzene

: 908013-49-0
(1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-aminoethylbenzene

: 1005795-38-9
(1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-(1-aminoethyl)-4-bromobenzene

Guidance literature:: With Rh₂{(S)-nta}4; bis(tertbutylcarbonyloxy)iodobenzene; In methanol; 1,1,2,2-tetrachloroethane; at -35 ℃; for 72h; Inert atmosphere; Molecular sieve;
DOI:10.1039/c0dt00283f

Reference yield:

: (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-aminoethylbenzene

: 1005795-38-9
(1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-(1-aminoethyl)-4-bromobenzene

Guidance literature:: Multi-step reaction with 2 steps

1: trifluoroacetic acid / 40 h / 35 °C

2: Rh₂{(S)-nta}4; bis(tertbutylcarbonyloxy)iodobenzene / methanol; 1,1,2,2-tetrachloroethane / 72 h / -35 °C / Inert atmosphere; Molecular sieve

With Rh₂{(S)-nta}4; bis(tertbutylcarbonyloxy)iodobenzene; trifluoroacetic acid; In methanol; 1,1,2,2-tetrachloroethane;
DOI:10.1039/c0dt00283f