816444-61-8Relevant articles and documents
Asymmetric Synthesis of amines through rhodium-catalyzed C-H amination with sulfonimidoylnitrenes
Darses, Benjamin,Jarvis, Amandag.,Mafroud, Abdel-Kader,Estenne-Bouhtou, Genevieve,Dargazanli, Gihad,Dauban, Philippe
, p. 2079 - 2087 (2013/08/23)
An efficient asymmetric C-H amination of benzylic and allylic substrates, as well as of adamantane derivatives, through catalytic C-H insertion of a chiral nitrene is reported. The reaction involves a chiral rhodium(II) complex, an iodine(III) oxidant, an
Catalytic stereoselective alkene aziridination with sulfonimidamides
Robert-Peillard, Fabien,Di Chenna, Pablo H.,Liang, Chungen,Lescot, Camille,Collet, Florence,Dodd, Robert H.,Dauban, Philippe
experimental part, p. 1447 - 1457 (2010/11/04)
Diastereoselective copper-catalyzed alkene aziridination has been investigated using chiral nitrenes generated from sulfonimidamides in the presence of an iodine(III) oxidant. Starting from a stoichiometric amount of the substrates, the corresponding azir
Stereoselective rhodium-catalyzed lmination of sulfides
Collet, Florence,Dodd, Robert H.,Dauban, Philippe
supporting information; experimental part, p. 5473 - 5476 (2009/06/06)
(Chemical Equation Presented) The preparation of optically active sulfilimines via the catalytic diastereoselective imination of sulfides using a chiral nitrene is described. Excellent yields up to 97% and good diastereoselectivities up to 96% have been obtained. Oxidation of the sulfilimines then stereospecifically affords the corresponding sulfoximines with very good yields in the 88-96% range.