(methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside

Base Information

Chemical Name:(methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside
CAS No.:911385-81-4
Molecular Formula:C₅₆H₆₂O₈SeSi
Molecular Weight:970.149
Hs Code.:

(methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside

Synonyms:(methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside

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Chemical Property of (methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside

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Technology Process of (methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside

There total 3 articles about (methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3427-20-1
methyl 4,6-di-O-acetyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside

: 911385-81-4
(methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / NaOMe / methanol

2: 58 percent / imidazole / dimethylformamide

3: 145 mg / acetonitrile

With 1H-imidazole; sodium methylate; In methanol; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1055/s-2006-942407

Reference yield:

: 23339-19-7
methyl-2,3-dideoxy-D-erythro-hex-2-enopyranoside

: 911385-81-4
(methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 58 percent / imidazole / dimethylformamide

2: 145 mg / acetonitrile

With 1H-imidazole; In N,N-dimethyl-formamide; acetonitrile;
DOI:10.1055/s-2006-942407

Reference yield:

: 2873-29-2
D-glucal triacetate

: 911385-81-4
(methyl-6-O-tert-butyldiphenylsilyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranos-4-yl)-3,4,6-tri-O-benzyl-2'-deoxy-2'-phenylselenyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 80 percent / BF₃*Et₂O

2: 87 percent / NaOMe / methanol

3: 58 percent / imidazole / dimethylformamide

4: 145 mg / acetonitrile

With 1H-imidazole; boron trifluoride diethyl etherate; sodium methylate; In methanol; N,N-dimethyl-formamide; acetonitrile; 1: Ferrier rearrangement;
DOI:10.1055/s-2006-942407