methyl 2-formyl-1-phenyl cyclopropanecarboxylate

Base Information

Chemical Name:methyl 2-formyl-1-phenyl cyclopropanecarboxylate
CAS No.:1035812-17-9
Molecular Formula:C₁₂H₁₂O₃
Molecular Weight:204.225
Hs Code.:

Synonyms:methyl 2-formyl-1-phenyl cyclopropanecarboxylate

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Chemical Property of methyl 2-formyl-1-phenyl cyclopropanecarboxylate

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Technology Process of methyl 2-formyl-1-phenyl cyclopropanecarboxylate

There total 4 articles about methyl 2-formyl-1-phenyl cyclopropanecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 201230-82-2
carbon monoxide

: 570431-52-6
1-phenylcycloprop-2-ene carboxylic acid methyl ester

: 1035812-17-9
methyl 2-formyl-1-phenyl cyclopropanecarboxylate

Guidance literature:: With 1,1'-bis(diphenylphosphino)ferrocene; Rh(acac)2(CO)2; hydrogen; In toluene; at 60 ℃; for 18h; under 7757.43 Torr; Inert atmosphere; Autoclave;
DOI:10.1021/ja805059f

Reference yield: 86.0%

: 1403365-70-7
(E)-methyl 1-phenyl-2-styrylcyclopropanecarboxylate

: 1035812-17-9
methyl 2-formyl-1-phenyl cyclopropanecarboxylate

Guidance literature:: (E)-methyl 1-phenyl-2-styrylcyclopropanecarboxylate; With ozone; In dichloromethane; at -78 ℃;

With triphenylphosphine; In dichloromethane; at 20 ℃; for 2h;

Reference yield:

: 14371-10-9
(E)-3-phenylpropenal

: 1035812-17-9
methyl 2-formyl-1-phenyl cyclopropanecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium tert-butylate / tetrahydrofuran / 5 h / 0 °C

1.2: 17 h / 0 °C / Inert atmosphere

2.1: dirhodium tetraacetate / toluene / 3 h / 20 °C / Inert atmosphere

3.1: ozone / dichloromethane / -78 °C

3.2: 2 h / 20 °C

With potassium tert-butylate; ozone; dirhodium tetraacetate; In tetrahydrofuran; dichloromethane; toluene;