benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate

Base Information

Chemical Name:benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate
CAS No.:918828-71-4
Molecular Formula:C₂₉H₃₄FNO₃Si
Molecular Weight:491.678
Hs Code.:

Synonyms:benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate

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Chemical Property of benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate

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Technology Process of benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate

There total 8 articles about benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 918828-70-3
C₃₅H₃₇FN₂O₇SSi

: 918828-71-4
benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate

Guidance literature:: With potassium carbonate; 4-t-butylbenzenethiol; In N,N-dimethyl-formamide; at 20 ℃; for 0.25h;
DOI:10.1016/j.tet.2006.09.096

Reference yield:

: 918828-69-0
(Z)-5-([tert-butyl(diphenyl)silyl]oxy)-2-fluoro-2-penten-1-ol

: 918828-71-4
benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate

Guidance literature:: Multi-step reaction with 2 steps

1: PPh₃; diethyl azodicarboxylate / CH₂Cl₂; toluene / 1 h / 20 °C

2: 230 mg / potassium carbonate; 4-tert-butyl(thiophenol) / dimethylformamide / 0.25 h / 20 °C

With potassium carbonate; 4-t-butylbenzenethiol; triphenylphosphine; diethylazodicarboxylate; In dichloromethane; N,N-dimethyl-formamide; toluene; 1: Mitsunobu reaction;
DOI:10.1016/j.tet.2006.09.096

Reference yield:

: 918667-14-8
ethyl (Z)-5-([tert-butyl(diphenyl)silyl]oxy)-2-fluoro-2-pentenoate

: 918828-71-4
benzyl (Z)-5-(tert-butyldiphenylsilyloxy)-2-fluoropent-2-enylcarbamate

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / LiAlH₄ / tetrahydrofuran / 0.5 h / 0 °C

2: PPh₃; diethyl azodicarboxylate / CH₂Cl₂; toluene / 1 h / 20 °C

3: 230 mg / potassium carbonate; 4-tert-butyl(thiophenol) / dimethylformamide / 0.25 h / 20 °C

With lithium aluminium tetrahydride; potassium carbonate; 4-t-butylbenzenethiol; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene; 2: Mitsunobu reaction;
DOI:10.1016/j.tet.2006.09.096