[Ru((E)-η1-C(C.ident.CPh)=CHPh)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)]

Base Information

Chemical Name:[Ru((E)-η1-C(C.ident.CPh)=CHPh)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)]
CAS No.:476489-10-8
Molecular Formula:C₅₀H₄₀P₂Ru
Molecular Weight:803.885
Hs Code.:

Synonyms:[Ru((E)-η1-C(C.ident.CPh)=CHPh)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)]

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Chemical Property of [Ru((E)-η1-C(C.ident.CPh)=CHPh)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)]

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Technology Process of [Ru((E)-η1-C(C.ident.CPh)=CHPh)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)]

There total 2 articles about [Ru((E)-η1-C(C.ident.CPh)=CHPh)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 476489-12-0
[Ru(=C(C.ident.CPh)CH2Ph)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)][BF4]

: 476489-10-8
[Ru((E)-η1-C(C.ident.CPh)=CHPh)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)]

Guidance literature:: With (CH₃)3COK; In tetrahydrofuran; (N2); stirring a mixt. of ruthenium complex with tert-BuOK in THF for 30min; evapn., extn. with Et2O, filtration;
DOI:10.1021/om020483a

Reference yield: 58.0%

: 199189-25-8
(η5-indenyl)(1,1'-bis(diphenylphosphanyl)methane)hydridoruthenium(II)

: 886-66-8
1,4-diphenyl-1,3-butadiyne

: 476489-10-8
[Ru((E)-η1-C(C.ident.CPh)=CHPh)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)]

Guidance literature:: In toluene; (N2); refluxing a soln. of ruthenium complex with excess diyne in toluene for 90 min; evapn., washing with pentane, drying in vac.;
DOI:10.1021/om020483a

Reference yield: 94.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 476489-10-8
[Ru((E)-η1-C(C.ident.CPh)=CHPh)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)]

: 476489-12-0
[Ru(=C(C.ident.CPh)CH2Ph)(η5-indenyl)(κ2-P-bis(diphenylphosphino)methane)][BF4]

Guidance literature:: In diethyl ether; (N2); dropwise addn. of a soln. of acid in Et2O to a soln. of ruthenium complex in Et2O at -40°C; decantation, washing with Et2O, drying in vac.;
DOI:10.1021/om020483a