(2E,4E,6S,7S,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenylundeca-2,4,10-trienoate

Base Information

Chemical Name:(2E,4E,6S,7S,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenylundeca-2,4,10-trienoate
CAS No.:405150-67-6
Molecular Formula:C₂₃H₃₂O₄
Molecular Weight:372.505
Hs Code.:

Synonyms:(2E,4E,6S,7S,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenylundeca-2,4,10-trienoate

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Chemical Property of (2E,4E,6S,7S,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenylundeca-2,4,10-trienoate

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Technology Process of (2E,4E,6S,7S,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenylundeca-2,4,10-trienoate

There total 3 articles about (2E,4E,6S,7S,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenylundeca-2,4,10-trienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 35588-79-5
(E)-3-iodobut-2-enoic acid methyl ester

: tributyl((1E,3S,4S,5R,6S,7E)-4,6-dimethoxy-3,5-dimethyl-8-phenylocta-1,7-dienyl)stannane

: 405150-67-6
(2E,4E,6S,7S,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenylundeca-2,4,10-trienoate

Guidance literature:: With 1-methyl-pyrrolidin-2-one; triphenyl-arsane; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾;
DOI:10.1021/ol017092x

Reference yield: 67.0%

: (2E,6R,7R,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenyl-5-(phenylsulfonyl)undeca-2,10-dienoate

: 405150-67-6
(2E,4E,6S,7S,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenylundeca-2,4,10-trienoate

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at -15 - -5 ℃; for 1.5h; Inert atmosphere;
DOI:10.1246/bcsj.20140271

Reference yield:

: 35588-79-5
(E)-3-iodobut-2-enoic acid methyl ester

: 213203-63-5
tri-n-butyl(diiodomethyl)stannane

: 329362-90-5
(2R,3R,4R,5S,E)-3,5-dimethoxy-2,4-dimethyl-7-phenylhept-6-enal

: 405150-67-6
(2E,4E,6S,7S,8R,9S,10E)-methyl 7,9-dimethoxy-3,6,8-trimethyl-11-phenylundeca-2,4,10-trienoate

Guidance literature:: tri-n-butyl(diiodomethyl)stannane; (2R,3R,4R,5S,E)-3,5-dimethoxy-2,4-dimethyl-7-phenylhept-6-enal; With chromium dichloride; In N,N-dimethyl-formamide; for 1.5h;

(E)-3-iodobut-2-enoic acid methyl ester; With triphenyl-arsane; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In 1-methyl-pyrrolidin-2-one; at 60 ℃; for 5h; Further stages.;
DOI:10.1016/j.tet.2008.01.139