methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside

Base Information

Chemical Name:methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside
CAS No.:196859-72-0
Molecular Formula:C₂₉H₄₂O₁₁
Molecular Weight:566.646
Hs Code.:

Synonyms:methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside

Suppliers and Price of methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside

There total 3 articles about methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 100-39-0
benzyl bromide

: 184776-05-4
(R)-2-[(3aR,5R,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy]-1-((3aS,4R,6S,6aS)-6-methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-ethanol

: 196859-72-0
methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; Ambient temperature;
DOI:10.1080/07328309708005739

Reference yield:

: 127244-81-9
methyl 2,3-O-isopropylidene-α-D-mannofuranoside 5,6-O-cyclic sulfate

: 196859-72-0
methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / H₂SO₄ / tetrahydrofuran; hexamethylphosphoric acid triamide

2: 96 percent / NaH / dimethylformamide / Ambient temperature

With sulfuric acid; sodium hydride; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.1080/07328309708005739

Reference yield:

: Lithium; (3aR,5S,6S,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-olate

: 196859-72-0
methyl 6-O-(3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-glucofuranos-3-yl)-2,3-O-isopropylidene-5-O-benzyl-α-D-mannofuranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 70 percent / H₂SO₄ / tetrahydrofuran; hexamethylphosphoric acid triamide

2: 96 percent / NaH / dimethylformamide / Ambient temperature

With sulfuric acid; sodium hydride; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.1080/07328309708005739