11-[β-(N-methyl-N-phenoxycarbonylamino)ethylthio]-2-(methylthio)-dibenz[b,f]oxepin

Base Information

Chemical Name:11-[β-(N-methyl-N-phenoxycarbonylamino)ethylthio]-2-(methylthio)-dibenz[b,f]oxepin
CAS No.:72281-18-6
Molecular Formula:C₂₅H₂₃NO₃S₂
Molecular Weight:449.595
Hs Code.:

Synonyms:11-[β-(N-methyl-N-phenoxycarbonylamino)ethylthio]-2-(methylthio)-dibenz[b,f]oxepin

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Chemical Property of 11-[β-(N-methyl-N-phenoxycarbonylamino)ethylthio]-2-(methylthio)-dibenz[b,f]oxepin

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Technology Process of 11-[β-(N-methyl-N-phenoxycarbonylamino)ethylthio]-2-(methylthio)-dibenz[b,f]oxepin

There total 5 articles about 11-[β-(N-methyl-N-phenoxycarbonylamino)ethylthio]-2-(methylthio)-dibenz[b,f]oxepin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 72281-11-9
11-[β-(dimethylamino)ethylthio]-2-(methylthio)dibenz[b,f]oxepin

: 1885-14-9
phenyl chloroformate

: 72281-18-6
11-[β-(N-methyl-N-phenoxycarbonylamino)ethylthio]-2-(methylthio)-dibenz[b,f]oxepin

Guidance literature:: With potassium carbonate; In dichloromethane; for 24h; Ambient temperature;
DOI:10.1021/jm00179a005

Reference yield:

: 25558-67-2
10,11-dihydro-2-(methylthio)-11-oxodibenzoxepin

: 72281-18-6
11-[β-(N-methyl-N-phenoxycarbonylamino)ethylthio]-2-(methylthio)-dibenz[b,f]oxepin

Guidance literature:: Multi-step reaction with 2 steps

1: boron trifluoride / acetic acid / 1.) RT, 16 h, 2.) reflux, 30 min

2: 72 percent / K₂CO₃ / CH₂Cl₂ / 24 h / Ambient temperature

With boron trifluoride; potassium carbonate; In dichloromethane; acetic acid;
DOI:10.1021/jm00179a005

Reference yield:

: 25563-01-3
2-(4-Methylmercapto-phenoxy)-phenylacetonitril

: 72281-18-6
11-[β-(N-methyl-N-phenoxycarbonylamino)ethylthio]-2-(methylthio)-dibenz[b,f]oxepin

Guidance literature:: Multi-step reaction with 5 steps

1: 82 percent / KOH / ethanol; H₂O / 3 h / Heating

2: thionylchloride / 0.17 h / Heating

3: AlCl₃ / 1,2-dichloro-ethane / 2 h / Heating

4: boron trifluoride / acetic acid / 1.) RT, 16 h, 2.) reflux, 30 min

5: 72 percent / K₂CO₃ / CH₂Cl₂ / 24 h / Ambient temperature

With potassium hydroxide; aluminium trichloride; thionyl chloride; boron trifluoride; potassium carbonate; In ethanol; dichloromethane; water; acetic acid; 1,2-dichloro-ethane;
DOI:10.1021/jm00179a005