2-[(3S,4S)-4-Hydroxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetrahydroxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester

Base Information

• Chemical Name: 2-[(3S,4S)-4-Hydroxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetrahydroxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester
• CAS No.: 79786-06-4
• Molecular Formula: C₂₇H₃₄O₁₅
• Molecular Weight: 598.558
• Mol file: 79786-06-4.mol

Synonyms:2-[(3S,4S)-4-Hydroxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetrahydroxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester

Chemical Property of 2-[(3S,4S)-4-Hydroxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetrahydroxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-[(3S,4S)-4-Hydroxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetrahydroxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester

There total 2 articles about 2-[(3S,4S)-4-Hydroxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetrahydroxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

diazomethane (186581-53-3,908094-01-9,334-88-3) + stachyurin pentadecamethyl ether (79786-02-0,87984-64-3) → 3,4,5-trimethoxybenzoic acid methyl ester (1916-07-0) + 4,5,6,4',5',6'-Hexamethoxy-biphenyl-2,2'-dicarboxylic acid dimethyl ester (4891-62-7,65995-60-0,71307-89-6) + 2-[(3S,4S)-4-Hydroxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetrahydroxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester (79786-06-4)

Guidance literature:

With sodium methylate; Yield given. Multistep reaction. Yields of byproduct given; 1.) methanol, RT, 16 h, 2.) ether, 20 min;

DOI:10.1039/P19830001765

Reference yield:

sodium methylate (124-41-4) + C64H60O30 (103488-40-0) → dimethyl (S,S)-decamethyl-gallagiate (65995-59-7) + 2-[(3S,4S)-4-Hydroxy-5,6,7-trimethoxy-1-oxo-3-((1S,2R,3R)-1,2,3,4-tetrahydroxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester (79786-06-4)

Guidance literature:

In methanol; for 168h; Product distribution; Ambient temperature;

DOI:10.1248/cpb.34.656

Reference yield:

acetic anhydride (108-24-7) + 2-[(3S,4S)-4-Hydroxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetrahydroxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester (79786-06-4) → 2-[(3S,4S)-4-Acetoxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetraacetoxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester (79786-07-5)

Guidance literature:

With pyridine; Ambient temperature;

DOI:10.1039/P19830001765

upstream raw materials:

sodium methylate

C₆₄H₆₀O₃₀

diazomethane

stachyurin pentadecamethyl ether

Downstream raw materials:

2-[(3S,4S)-4-Acetoxy-5,6,7-trimethoxy-1-oxo-3-(1,2,3,4-tetraacetoxy-butyl)-isochroman-8-yl]-3,4,5-trimethoxy-benzoic acid methyl ester