dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Base Information

Chemical Name:dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside
CAS No.:315208-40-3
Molecular Formula:C₂₉H₄₁NO₉Si
Molecular Weight:575.731
Hs Code.:

Synonyms:dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Suppliers and Price of dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

There total 7 articles about dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 100-47-0
benzonitrile

: 315208-39-0
dimethyl(thexyl)silyl 3-O-acetyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

: 315208-40-3
dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Guidance literature:: With triethylamine; propiononitrile; at 20 ℃; for 1.5h;
DOI:10.1002/1099-0690(200011)2000:21<3541::aid-ejoc3541>3.3.co;2-b

Reference yield:

: 67373-56-2
chlorodimethyl(1,1,2-trimethylpropyl)silane

: 315208-40-3
dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 87 percent / imidazole / CH₂Cl₂ / 16 h / 20 °C

2: 98 percent / sodium methoxide / methanol / 4 h / 20 °C

3: 86 percent / pTsOH / acetonitrile / 16 h / 20 °C

4: 100 percent / pyridine / 1 h / 20 °C

5: 86 percent / ethanethiol; pTsOH / CH₂Cl₂ / 2 h / 20 °C

6: 87 percent / triethylamine; propionitrile / 1.5 h / 20 °C

With pyridine; 1H-imidazole; sodium methylate; toluene-4-sulfonic acid; triethylamine; ethanethiol; propiononitrile; In methanol; dichloromethane; acetonitrile; 1: Condensation / 2: Deacetylation / 3: Etherification / 4: Acetylation / 5: Ring cleavage / 6: Acylation;
DOI:10.1002/1099-0690(200011)2000:21<3541::aid-ejoc3541>3.3.co;2-b

Reference yield:

: 303082-31-7
dimethyl(thexyl)silyl 4,6-O-benzylidene-2-deoxy-2-(dimethylmaleimido)-β-D-glucopyranoside

: 315208-40-3
dimethyl(thexyl)silyl 3-O-acetyl-6-O-benzoyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / pyridine / 1 h / 20 °C

2: 86 percent / ethanethiol; pTsOH / CH₂Cl₂ / 2 h / 20 °C

3: 87 percent / triethylamine; propionitrile / 1.5 h / 20 °C

With pyridine; toluene-4-sulfonic acid; triethylamine; ethanethiol; propiononitrile; In dichloromethane; 1: Acetylation / 2: Ring cleavage / 3: Acylation;
DOI:10.1002/1099-0690(200011)2000:21<3541::aid-ejoc3541>3.3.co;2-b