Technology Process of Benzenemethanamine, alpha-methyl-N-(2-methylphenyl)-, rel-(-)- (9CI)
There total 6 articles about Benzenemethanamine, alpha-methyl-N-(2-methylphenyl)-, rel-(-)- (9CI) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
bis(1,5-cyclooctadiene)diiridium(I) dichloride; C46H50FeP2; hydrogen; tetra-(n-butyl)ammonium iodide; trifluoroacetic acid;
In
toluene;
at 50 ℃;
for 12h;
under 15201 - 38002.6 Torr;
enantioselective reaction;
DOI:10.1016/j.catcom.2019.105906
- Guidance literature:
-
With
triethylsilane; trifluoroacetic acid;
In
dichloromethane;
at 20 ℃;
for 2h;
Inert atmosphere;
DOI:10.1021/acs.orglett.8b03093
- Guidance literature:
-
With
(S)-4-(pentafluorophenyl)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]borepine tetrahydrofuran; Dimethylphenylsilane;
at 20 ℃;
for 17h;
Overall yield = 94 %; enantioselective reaction;
Glovebox;
DOI:10.1002/chem.201202693