2-{2-[(tert-butoxycarbonyl)amino]phenyl}buta-2,3-dien-1-yl ethyl carbonate

Base Information

• Chemical Name: 2-{2-[(tert-butoxycarbonyl)amino]phenyl}buta-2,3-dien-1-yl ethyl carbonate
• CAS No.: 1179444-87-1
• Molecular Formula: C₁₈H₂₃NO₅
• Molecular Weight: 333.384
• Mol file: 1179444-87-1.mol

Synonyms:2-{2-[(tert-butoxycarbonyl)amino]phenyl}buta-2,3-dien-1-yl ethyl carbonate

Chemical Property of 2-{2-[(tert-butoxycarbonyl)amino]phenyl}buta-2,3-dien-1-yl ethyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-{2-[(tert-butoxycarbonyl)amino]phenyl}buta-2,3-dien-1-yl ethyl carbonate

There total 1 articles about 2-{2-[(tert-butoxycarbonyl)amino]phenyl}buta-2,3-dien-1-yl ethyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

N-(tert-butoxycarbonyl)-2-(1-hydroxy-2,3-butadien-2-yl)aniline (958882-75-2) + chloroformic acid ethyl ester (541-41-3) → 2-{2-[(tert-butoxycarbonyl)amino]phenyl}buta-2,3-dien-1-yl ethyl carbonate (1179444-87-1)

Guidance literature:

With pyridine; at 0 - 20 ℃; for 4h; Inert atmosphere;

DOI:10.1021/jo901325d

Reference yield: 94.0%

N-phenyl-maleimide (941-69-5) + 2-{2-[(tert-butoxycarbonyl)amino]phenyl}buta-2,3-dien-1-yl ethyl carbonate (1179444-87-1) → tert-butyl (+/-)-(3aR*,10aS*)-1,3,3a,4,10,10a-hexahydro-1,3-dioxo-2-phenyl-5H-pyrrolo[3,4-b]carbazole-5-carboxylate

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In toluene; at 120 ℃; Inert atmosphere;

DOI:10.1021/jo901325d

Reference yield: 67.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 2-{2-[(tert-butoxycarbonyl)amino]phenyl}buta-2,3-dien-1-yl ethyl carbonate (1179444-87-1) → tert-butyl 1,2,3,4-tetrahydro-2-phenyl-9H-carbazole-9-carboxylate (1179445-01-2) + C30H34N2O4 (83020-28-4)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In toluene; at 120 ℃; Inert atmosphere;

DOI:10.1021/jo901325d

upstream raw materials:

N-(tert-butoxycarbonyl)-2-(1-hydroxy-2,3-butadien-2-yl)aniline

chloroformic acid ethyl ester

Downstream raw materials:

tert-butyl 1,2,3,4-tetrahydro-2-phenyl-9H-carbazole-9-carboxylate

C₃₀H₃₄N₂O₄

tert-butyl 1,2,3,4-tetrahydro-3-phenyl-9H-carbazole-9-carboxylate

hexamethyl benzenehexacarboxylate