Mo(N₂)2(P(C₆H₅)2(CH₃))4*C₆H₆

Base Information

• Chemical Name: Mo(N₂)2(P(C₆H₅)2(CH₃))4*C₆H₆
• CAS No.: 33248-03-2
• Molecular Formula: C₆H₆*C₅₂H₅₂MoN₄P₄
• Molecular Weight: 1030.96
• Mol file: 33248-03-2.mol

Synonyms:Mo(N₂)2(P(C₆H₅)2(CH₃))4*C₆H₆

Chemical Property of Mo(N₂)2(P(C₆H₅)2(CH₃))4*C₆H₆

Chemical Property:

Purity/Quality:

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Technology Process of Mo(N₂)2(P(C₆H₅)2(CH₃))4*C₆H₆

There total 1 articles about Mo(N₂)2(P(C₆H₅)2(CH₃))4*C₆H₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

trichlorotris(tetrahydrofuran)molybdenum(III) (31355-55-2,39210-30-5) + diphenyl(methyl)phosphine (1486-28-8) → Mo(N2)2(P(C6H5)2(CH3))4*C6H6 (33248-03-2)

Guidance literature:

With sodium amalgam; benzene; In tetrahydrofuran; benzene; to soln. MoCl3(THF)3 in THF added PPh2Me and sodium amalgam, N2 bubbledfor 1 h and mixt. stirred for total 4 h, soln. filtered, THF removed, solid dissolved in benzene; soln. filtered, methanol added and chilled at 0°C, solid filtered, washed with methanol and dried in vacuo; elem. anal.;

DOI:10.1021/ic50215a061

Reference yield: 81.0%

Mo(N2)2(PPh2Me)4 (33248-03-2,66008-09-1,115461-51-3) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → trans-[1,2-bis(diphenylphosphino)ethane]bis(dinitrogen)bis(methyldiphenylphosphine)molybdenum (65498-66-0)

Guidance literature:

In benzene; to soln. Mo(N2)2(PPh2Me)4 in benzene dppe added and mixt. stirred for 2h; chilled methanol at 0°C added and mixt. allowed to stand in 5°C refrigerator for 16 h, solid filtered, washed with methanol and dried in vacuo; elem. anal.;

DOI:10.1021/ic50215a061

Reference yield: 58.0%

Mo(N2)2(PPh2Me)4 (33248-03-2,66008-09-1,115461-51-3) + 13-(2-(bis(2-(diisopropylphosphaneyl)ethyl)phosphaneyl)ethyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane → mer-(15-Crown-iPr)Mo(N2)2(PPh2Me)

Guidance literature:

In tetrahydrofuran; for 9h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/c9dt01606f

upstream raw materials:

trichlorotris(tetrahydrofuran)molybdenum(III)

diphenyl(methyl)phosphine

Downstream raw materials:

trans-[1,2-bis(diphenylphosphino)ethane]bis(dinitrogen)bis(methyldiphenylphosphine)molybdenum

trans-[Mo(N₂)2(bis(diphenylphosphinoethyl)phenylphosphine)(PMePh₂)]

{Mo(H)2(S₂C₂H₄)(PCH₃(C₆H₅)2)3}

{Mo(H)2(S₂C₆H₄)(PCH₃(C₆H₅)2)3}