8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine

Base Information

Chemical Name:8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine
CAS No.:1297529-98-6
Molecular Formula:C₂₃H₂₁NO₅
Molecular Weight:391.423
Hs Code.:

Synonyms:8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine

Suppliers and Price of 8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine

There total 5 articles about 8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 1297529-90-8
[2-(6-bromo-benzo[1,3]dioxol-5-ylmethoxy)-3-methoxybenzyl]-(4-methoxy-phenyl)-amine

: 1297529-98-6
8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine

Guidance literature:: With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium tert-butylate; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; for 17h; Reflux; Inert atmosphere;
DOI:10.1016/j.ejmech.2011.02.024

Reference yield:

: C₂₃H₂₀BrNO₅

: 1297529-98-6
8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine

Guidance literature:: Multi-step reaction with 2 steps

1: sodium tetrahydroborate / ethanol / 2 h / 0 °C

2: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium tert-butylate; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / 17 h / Reflux; Inert atmosphere

With sodium tetrahydroborate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium tert-butylate; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In ethanol;
DOI:10.1016/j.ejmech.2011.02.024

Reference yield:

: 5434-47-9
5-bromo-6-bromomethylbenzo[1,3]dioxole

: 1297529-98-6
8,9-(methylenedioxy)-4-methoxy-11-[4-methoxy-phenyl]-11,12-dihydro-6H-dibenz[b,f][1,5]oxazocine

Guidance literature:: Multi-step reaction with 4 steps

1: potassium carbonate / acetone / 3 h / Reflux

2: ethanol / 12 h / 25 °C

3: sodium tetrahydroborate / ethanol / 2 h / 0 °C

4: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium tert-butylate; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / 17 h / Reflux; Inert atmosphere

With sodium tetrahydroborate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium tert-butylate; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In ethanol; acetone;
DOI:10.1016/j.ejmech.2011.02.024