Bicyclo[2.2.1]hept-5-en-2-ol, 1,7,7-trimethyl-2-(1-methylethyl)-, (1S,2R,4R)- (9CI)

Base Information

Chemical Name:Bicyclo[2.2.1]hept-5-en-2-ol, 1,7,7-trimethyl-2-(1-methylethyl)-, (1S,2R,4R)- (9CI)
CAS No.:791104-79-5
Molecular Formula:C₁₃H₂₂O
Molecular Weight:194.317
Hs Code.:
Mol file:791104-79-5.mol

Synonyms:Bicyclo[2.2.1]hept-5-en-2-ol, 1,7,7-trimethyl-2-(1-methylethyl)-, (1S,2R,4R)- (9CI)

Suppliers and Price of Bicyclo[2.2.1]hept-5-en-2-ol, 1,7,7-trimethyl-2-(1-methylethyl)-, (1S,2R,4R)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Bicyclo[2.2.1]hept-5-en-2-ol, 1,7,7-trimethyl-2-(1-methylethyl)-, (1S,2R,4R)- (9CI)

Chemical Property:

PSA：20.23000
LogP:2.99570

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Bicyclo[2.2.1]hept-5-en-2-ol, 1,7,7-trimethyl-2-(1-methylethyl)-, (1S,2R,4R)- (9CI)

There total 3 articles about Bicyclo[2.2.1]hept-5-en-2-ol, 1,7,7-trimethyl-2-(1-methylethyl)-, (1S,2R,4R)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1068-55-9
isopropylmagnesium chloride

: 104832-00-0
(1S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-5-en-2-one

: 791104-79-5
(1S,2R,4R)-1,7,7-trimethyl-2-(1-methylethyl)bicyclo[2.2.1]hept-5-en-2-ol

Guidance literature:: With cerium(III) chloride; In tetrahydrofuran; at 20 ℃; for 0.5h;
DOI:10.1002/hlca.200490179

Reference yield:

: 10293-06-8
(1R)-3-endo-bromocamphor

: 791104-79-5
(1S,2R,4R)-1,7,7-trimethyl-2-(1-methylethyl)bicyclo[2.2.1]hept-5-en-2-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 42 percent / chlorosulfonic acid / 0.33 h / 45 °C

2: 45 percent / KOH / dimethylsulfoxide; H₂O / 2.5 h / 120 °C

3: 93 percent / CeCl₃ / tetrahydrofuran / 0.5 h / 20 °C

With chlorosulfonic acid; potassium hydroxide; cerium(III) chloride; In tetrahydrofuran; water; dimethyl sulfoxide;
DOI:10.1002/hlca.200490179

Reference yield:

: 33171-48-1
(1S,4R,6S)-6-bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one

: 791104-79-5
(1S,2R,4R)-1,7,7-trimethyl-2-(1-methylethyl)bicyclo[2.2.1]hept-5-en-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 45 percent / KOH / dimethylsulfoxide; H₂O / 2.5 h / 120 °C

2: 93 percent / CeCl₃ / tetrahydrofuran / 0.5 h / 20 °C

With potassium hydroxide; cerium(III) chloride; In tetrahydrofuran; water; dimethyl sulfoxide;
DOI:10.1002/hlca.200490179