4-Nitrobenzyl carbanilate

Base Information

Chemical Name:4-Nitrobenzyl carbanilate
CAS No.:74109-32-3
Molecular Formula:C14H12 N2 O4
Molecular Weight:272.25608
Hs Code.:
European Community (EC) Number:667-587-9
ChEMBL ID:CHEMBL174673
Nikkaji Number:J3.600.593I
Mol file:74109-32-3.mol

Synonyms:CHEMBL174673;SCHEMBL10490780;4-NITROBENZYL CARBANILATE;AKOS024334287

Suppliers and Price of 4-Nitrobenzyl carbanilate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 4-Nitrobenzyl carbanilate

Chemical Property:

Melting Point:121 - 123 °C
PSA：84.15000
LogP:3.93970
XLogP3:2.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:4
Exact Mass:272.07970687
Heavy Atom Count:20
Complexity:329

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)NC(=O)OCC2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of 4-Nitrobenzyl carbanilate

There total 3 articles about 4-Nitrobenzyl carbanilate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 62-53-3
aniline

: 4457-32-3
4-nitrobenzyl chloroformate

: 74109-32-3
4-nitrobenzyl phenylcarbamate

Guidance literature:: With sodium hydrogencarbonate; In ethyl acetate; at 0 ℃; for 0.25h;

Reference yield: 87.0%

: 3422-01-3
tert-butyl phenylcarbamate

: 30039-42-0
4-nitrobenzyl formate

: 74109-32-3
4-nitrobenzyl phenylcarbamate

Guidance literature:: With cobalt(II) iodide; zinc; tris(p-dimethylaminophenyl)phosphine; In toluene; at 120 ℃; for 40h; Schlenk technique; Inert atmosphere; Glovebox;
DOI:10.1039/c9ob00924h

Reference yield: 77.0%

: 619-73-8
4-nitrobenzyl chloride

: 495-18-1
Benzohydroxamic acid

: 74109-32-3
4-nitrobenzyl phenylcarbamate

Guidance literature:: Benzohydroxamic acid; With dmap; ethyl 2-(tert-butoxycarbonyloxyimino)-2-cyanoacetate; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 ℃; for 0.25h; Green chemistry;

4-nitrobenzyl chloride; In dichloromethane; at 60 ℃; for 6h; chemoselective reaction; Green chemistry;
DOI:10.1002/adsc.201600661