[Fe(mesityl)(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

Base Information

• Chemical Name: [Fe(mesityl)(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]
• CAS No.: 1361229-44-8
• Molecular Formula: C₆₄H₈₂FeNP₂
• Molecular Weight: 983.156
• Mol file: 1361229-44-8.mol

Synonyms:[Fe(mesityl)(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

Chemical Property of [Fe(mesityl)(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Fe(mesityl)(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

There total 7 articles about [Fe(mesityl)(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

FeBr2(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine) (1236907-70-2) + 2-mesitylmagnesium bromide (2633-66-1) → [Fe(mesityl)(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)] (1361229-44-8)

Guidance literature:

In tetrahydrofuran; benzene; (under N2, Schlenk); Fe-complex dissolved in benzene, THF soln. of Mg-salt slowly added over 1 h at room temp.; solvent removed under vac., residue washed with hexane, extd. with benzene, filtered, filtrate concd. to dryness under vac.;

DOI:10.1021/om201280z

Reference yield: 70.0%

[FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)] (1236907-72-4) + Mes2MgTHF → [Fe(mesityl)(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)] (1361229-44-8)

Guidance literature:

In benzene; (under N2, Schlenk); Mg-salt in benzene added to benzene soln. of Fe-complex, stirred for 30 min at room temp.; filtered, solvent evapd., residue washed with hexane, dried under vac.;

DOI:10.1021/om201280z

Reference yield: 69.0%

Mes2MgTHF + FeBr2(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine) (1236907-70-2) → [Fe(mesityl)(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)] (1361229-44-8)

Guidance literature:

In benzene; (under N2, Schlenk); Mg-salt in benzene added to benzene soln. of Fe-complex, stirred for 1 h at room temp.; filtered, solvent removed under vac.;

DOI:10.1021/om201280z

upstream raw materials:

benzyl bromide

[FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

2-mesitylmagnesium bromide

FeBr₂(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)

Downstream raw materials:

C₅₄H₇₁FeN₃P₂Si₂

C₅₆H₇₁FeN₃P₂

C₆₄H₇₁FeN₃P₂

C₄₈H₅₃FeNO₂P₂