[FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

Base Information

Chemical Name:[FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]
CAS No.:1236907-72-4
Molecular Formula:C₅₅H₇₁BrFeNP₂
Molecular Weight:943.874
Hs Code.:

Synonyms:[FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

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Technology Process of [FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

There total 4 articles about [FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1236907-70-2
[((E,E)-C₅H₃N(C(Ph)P(2,4,6-tri-tert-butylphenyl))2)FeBr₂]

: 1236907-72-4
[FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

Guidance literature:: With KC₈; In benzene; treatment of iron compd. with 2 equiv. of KC8 in benzene at room temp.;
DOI:10.1021/ja102009n

Reference yield: 57.0%

: 1277-43-6,78206-33-4
cobaltocene

: 1236907-70-2
FeBr₂(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)

: 1236907-72-4
[FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

Guidance literature:: In benzene; (under N2, Schlenk); Fe-complex dissolved in benzene, benzene soln. of Co-complex added at room temp.; filtered, solvent removed under vac., residue washed with hexane, dried under vac.;
DOI:10.1021/om201280z

Reference yield: 22.0%

: 1236907-70-2
FeBr₂(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)

: 100-58-3
phenylmagnesium bromide

: 1236907-72-4
[FeBr(2,6-bis[1-phenyl-2-(2,4,6-tri-tert-butylphenyl)-2-phosphaethenyl]pyridine)]

Guidance literature:: In tetrahydrofuran; toluene; (under N2, Schlenk); Mg-salt in THF added to toluene soln. of Fe-complexat -78°C, stirred at room temp. for 2 h; concd. under vac., extd. with hexane, extract allowed to stand at -30°C, supernatant concd. to dryness;
DOI:10.1021/om201280z