4-tetradecyloxybenzoic acid 4-aminophenyl ester

Base Information

• Chemical Name: 4-tetradecyloxybenzoic acid 4-aminophenyl ester
• CAS No.: 163856-11-9
• Molecular Formula: C₂₇H₃₉NO₃
• Molecular Weight: 425.612
• Mol file: 163856-11-9.mol

Synonyms:4-tetradecyloxybenzoic acid 4-aminophenyl ester

Chemical Property of 4-tetradecyloxybenzoic acid 4-aminophenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 4-tetradecyloxybenzoic acid 4-aminophenyl ester

There total 6 articles about 4-tetradecyloxybenzoic acid 4-aminophenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

4-nitrophenyl 4-n-tetradecyloxybenzoate (68162-41-4) → 4-tetradecyloxybenzoic acid 4-aminophenyl ester (163856-11-9)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In methanol; benzene; for 4h; under 1900.13 Torr;

DOI:10.1080/10610270802709386

Reference yield:

4-(tetradecyloxy)benzoic acid (15872-46-5) → 4-tetradecyloxybenzoic acid 4-aminophenyl ester (163856-11-9)

Guidance literature:

Multi-step reaction with 2 steps

1: DCC; DMAP / CH₂Cl₂

2: H₂ / Pd/C / benzene / atmospheric pressure

With dmap; hydrogen; dicyclohexyl-carbodiimide; palladium on activated charcoal; In dichloromethane; benzene;

DOI:10.1039/b316731c

Reference yield:

1-Bromotetradecane (112-71-0) → 4-tetradecyloxybenzoic acid 4-aminophenyl ester (163856-11-9)

Guidance literature:

Multi-step reaction with 4 steps

1: K₂CO₃ / acetonitrile / Heating

2: KOH / ethanol / Heating

3: DCC; DMAP / CH₂Cl₂

4: H₂ / Pd/C / benzene / atmospheric pressure

With dmap; potassium hydroxide; hydrogen; potassium carbonate; dicyclohexyl-carbodiimide; palladium on activated charcoal; In ethanol; dichloromethane; acetonitrile; benzene; 1: Williamson alkylation;

DOI:10.1039/b316731c

upstream raw materials:

4-nitrophenyl 4-n-tetradecyloxybenzoate

1-Bromotetradecane

4-(tetradecyloxy)benzoic acid

methyl 4-tetradecyloxybenzoate

Downstream raw materials:

C₆₉H₈₇N₃O₆