[Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*0.25CH₂Cl₂=[Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*0.25CH₂Cl₂

Base Information

• Chemical Name: [Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*0.25CH₂Cl₂=[Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*0.25CH₂Cl₂
• CAS No.: 96616-80-7
• Molecular Formula: BF₄*0CH₂Cl₂*C₃₃H₂₅Ir₂N₂O₄P₂
• Molecular Weight: 1068
• Mol file: 96616-80-7.mol

Synonyms:[Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*0.25CH₂Cl₂=[Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*0.25CH₂Cl₂

Chemical Property of [Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*0.25CH₂Cl₂=[Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*0.25CH₂Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*0.25CH₂Cl₂=[Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*0.25CH₂Cl₂

There total 2 articles about [Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*0.25CH₂Cl₂=[Ir₂(CO)4(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*0.25CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[Ir2(C8H12)2(C3HN2(CH2P(C6H5)2)2)](1+)*BF4(1-)*CH3OH=[Ir2(C8H12)2(C3HN2(CH2P(C6H5)2)2)]BF4*CH3OH (96532-20-6) → [Ir2(CO)4(C3HN2(CH2P(C6H5)2)2)](1+)*BF4(1-)*0.25CH2Cl2=[Ir2(CO)4(C3HN2(CH2P(C6H5)2)2)]BF4*0.25CH2Cl2 (96616-80-7)

Guidance literature:

With carbon monoxide; In dichloromethane; byproducts: 1,5-cyclooctadiene; soln. of complex is treated with CO, further work-up under CO; addn. of hexane, recrystn. of ppt. from CH2Cl2/hexane, elem. anal.;

Reference yield:

[(cod)Ir(3,5-bis((diphenylphosphino)methyl)pyrazolato)Rh(cod)]BF4 (881493-81-8) + carbon monoxide (201230-82-2) → [(CO)2Rh(3,5-bis((diphenylphosphino)methyl)pyrazolato)Rh(CO)2]BF4 (96633-00-0) + [(CO)2Rh(3,5-bis((diphenylphosphino)methyl)pyrazolato)Ir(CO)2]BF4 (881913-65-1) + [(CO)2Ir(3,5-bis((diphenylphosphino)methyl)pyrazolato)Ir(CO)2]BF4 (96616-80-7)

Guidance literature:

In dichloromethane; soln. Rh-Ir complex in CH2Cl2 was stirred under CO atm. (1 atm.) at roomtemp.;

DOI:10.1021/om050897e

Reference yield: 53.0%

[(CO)2Ir(3,5-bis((diphenylphosphino)methyl)pyrazolato)Ir(CO)2]BF4 (96616-80-7) + trimethylsilylacetylene (1066-54-2) → (CO)Ir(3,5-bis((diphenylphosphino)methyl)pyrazolato)Ir(CO)(μ-CCSiMe3) (881914-02-9)

Guidance literature:

With n-BuLi; In tetrahydrofuran; under inert atm. to soln. HCCSiMe3 in THF at -75°C n-BuLi was added, after 10 min soln. Ir-Ir complex in THF was added and stirred for 10min at -75°C, for 30 min at 0°C, and for 1 h at room temp .; soln. was filtered through alumina and concd. in vacuo, Et2O was added; elem. anal.;

DOI:10.1021/om050897e

upstream raw materials:

[Ir₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]⁽¹⁺⁾*BF₄^(1-)*CH₃OH=[Ir₂(C₈H₁₂)2(C₃HN₂(CH₂P(C₆H₅)2)2)]BF₄*CH₃OH

[(cod)Ir(3,5-bis((diphenylphosphino)methyl)pyrazolato)Rh(cod)]BF₄

carbon monoxide

Downstream raw materials:

(CO)Ir(3,5-bis((diphenylphosphino)methyl)pyrazolato)Ir(CO)(μ-CC-p-tol)

(CO)Ir(3,5-bis((diphenylphosphino)methyl)pyrazolato)Ir(CO)(μ-CCSiMe3)