5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde

Base Information

• Chemical Name: 5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde
• CAS No.: 1257102-52-5
• Molecular Formula: C₃₁H₃₁NOS
• Molecular Weight: 465.659
• Mol file: 1257102-52-5.mol

Synonyms:5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde

Chemical Property of 5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde

There total 1 articles about 5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

thiophene-2-carbaldehyde (98-03-3) + 3,6-di-tert-butyl-9-(4-iodophenyl)-9H-carbazole (255829-32-4) → 5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde (1257102-52-5)

Guidance literature:

With 1,10-Phenanthroline; caesium carbonate; copper dichloride; In m-xylene; at 120 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1002/cssc.201700421

Reference yield: 66.0%

5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde (1257102-52-5) + C33H49Br2O3PS3 → C60H69Br2NS4

Guidance literature:

C₃₃H₄₉Br₂O₃PS₃; With sodium methylate; In N,N-dimethyl-formamide; Cooling with ice;

5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde; In N,N-dimethyl-formamide; at 0 ℃; for 2h;

DOI:10.1039/c3ta11272a

Reference yield: 66.0%

C33H49Br2O3PS3 (1448532-24-8) + 5-(4-(3,6-di-tert-butyl-9-carbazolyl)phenyl)thiophene-2-carbaldehyde (1257102-52-5) → C60H69Br2NS4 (1448532-25-9)

Guidance literature:

With sodium methylate; In N,N-dimethyl-formamide; for 2h; Cooling with ice;

DOI:10.1039/c3ta11272a

upstream raw materials:

thiophene-2-carbaldehyde

3,6-di-tert-butyl-9-(4-iodophenyl)-9H-carbazole

Downstream raw materials:

C₆₀H₆₉Br₂NS₄