[((AsPh3)(C6F5)Pd)2(μ-κ2-C,O-CH2C(O)CH3)2]

Base Information

• Chemical Name: [((AsPh3)(C6F5)Pd)2(μ-κ2-C,O-CH2C(O)CH3)2]
• CAS No.: 344863-11-2
• Molecular Formula: C₅₄H₄₀As₂F₁₀O₂Pd₂
• Molecular Weight: 1273.58
• Mol file: 344863-11-2.mol

Synonyms:[((AsPh3)(C6F5)Pd)2(μ-κ2-C,O-CH2C(O)CH3)2]

Chemical Property of [((AsPh3)(C6F5)Pd)2(μ-κ2-C,O-CH2C(O)CH3)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [((AsPh3)(C6F5)Pd)2(μ-κ2-C,O-CH2C(O)CH3)2]

There total 1 articles about [((AsPh3)(C6F5)Pd)2(μ-κ2-C,O-CH2C(O)CH3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

[(Pd(C6F5)(AsPh3)(μ-Cl))2] + acetone (67-64-1) → [((AsPh3)(C6F5)Pd)2(μ-κ2-C,O-CH2C(O)CH3)2] (344863-11-2)

Guidance literature:

With (NBu₄)OH; In water; acetone; to suspn. (((o-C6H4CH2NMe2)Pd(μ-OH))2) in acetone aq. (Bu4N)OH was added and stirred at room temp. for 30 min; soln. was concd. under vac., MeOH and H2O were added, ppt. was filtered off, air-dried, and dissolved in CH2Cl2, filtered, evapd. to dryness, Et2O/hexane was added, solid was filtered, air-dried and recrystd. from toluene/hexane; elem. anal.;

DOI:10.1021/om000860o

Reference yield: 70.0%

[((AsPh3)(C6F5)Pd)2(μ-κ2-C,O-CH2C(O)CH3)2] (344863-11-2) + tert-butylisonitrile (119072-55-8,7188-38-7) → [(AsPh3)(C6F5)Pd(CH2C(O)CH3)(t-BuNC)] (344863-15-6)

Guidance literature:

In dichloromethane; to soln. (((AsPh3)(C6F5)Pd)2(μ-CH2C(O)CH3)2) in CH2Cl2 was added t-BuNC, soln. was stirred at room temp. for 15 min; soln. was concd. under vac., hexane was added, ppt was filtered off, washed with hexane, and air-dried; elem. anal.;

DOI:10.1021/om000860o

upstream raw materials:

acetone

Downstream raw materials:

[(AsPh₃)(C₆F₅)Pd(CH₂C(O)CH₃)(t-BuNC)]