tris-(2-mercaptothiazoline)triphenylphosphinerhodium(I) chloride

Base Information

Chemical Name:tris-(2-mercaptothiazoline)triphenylphosphinerhodium(I) chloride
CAS No.:58723-79-8
Molecular Formula:C₂₇H₃₀N₃PRhS₆*Cl
Molecular Weight:758.284
Hs Code.:

Synonyms:tris-(2-mercaptothiazoline)triphenylphosphinerhodium(I) chloride

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Chemical Property of tris-(2-mercaptothiazoline)triphenylphosphinerhodium(I) chloride

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Technology Process of tris-(2-mercaptothiazoline)triphenylphosphinerhodium(I) chloride

There total 2 articles about tris-(2-mercaptothiazoline)triphenylphosphinerhodium(I) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 14694-95-2
Wilkinson's catalyst

: 96-53-7
2-mercaptothiazoline

: 58723-79-8
tris-(2-mercaptothiazoline)triphenylphosphinerhodium(I) chloride

Guidance literature:: With HCl; In ethanol; dichloromethane; addn. of hot soln. of Rh-complex (in CH2Cl2) to 4 equiv. of ligand (in hot EtOH), pH adjustment to 2 (1 M HCl); pptn. on Et2O addn., recrystn. (CH2Cl2/Et2O); elem. anal.;
DOI:10.1016/S0020-1693(00)81954-4

Reference yield:

: 14694-95-2
Wilkinson's catalyst

: 96-53-7
2-mercaptothiazoline

: 58723-79-8
{Rh(C₃H₅NS₂)3P(C₆H₅)3}⁽¹⁺⁾*Cl^(1-)={Rh(C₃H₅NS₂)3(P(C₆H₅)3)}Cl

Guidance literature:: With HCl; In ethanol; dichloromethane; treatment of Rh(PPh3)3Cl in hot CH2Cl2 with ligand in ethanol, mainted at pH=2 by addition of HCl;
DOI:10.1016/S0020-1693(00)81954-4

Reference yield: 75.0%

: ammonium hexafluorophosphate

: 58723-79-8
tris-(2-mercaptothiazoline)triphenylphosphinerhodium(I) chloride

: 59368-70-6
diiodotris-(2-mercaptothiazoline)triphenylphosphinerhodium(III) hexafluorophosphate

Guidance literature:: With MeI; In not given; addn. of excess MeI to soln. of Rh-complex, pptn. on NH4PF6 addn.; washing (EtOH), recrystn. (CH2Cl2/Et2O); elem. anal.;
DOI:10.1016/S0020-1693(00)81954-4