Li⁽¹⁺⁾*Mo(CO)3(C₅(CH₂C₆H₅)5)^(1-) = Li[Mo(CO)3(C₅(CH₂C₆H₅)5)]

Base Information

• Chemical Name: Li⁽¹⁺⁾*Mo(CO)3(C₅(CH₂C₆H₅)5)^(1-) = Li[Mo(CO)3(C₅(CH₂C₆H₅)5)]
• CAS No.: 740801-07-4
• Molecular Formula: C₄₃H₃₅MoO₃*Li
• Molecular Weight: 702.63
• Mol file: 740801-07-4.mol

Synonyms:Li⁽¹⁺⁾*Mo(CO)3(C₅(CH₂C₆H₅)5)^(1-) = Li[Mo(CO)3(C₅(CH₂C₆H₅)5)]

Chemical Property of Li⁽¹⁺⁾*Mo(CO)3(C₅(CH₂C₆H₅)5)^(1-) = Li[Mo(CO)3(C₅(CH₂C₆H₅)5)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Li⁽¹⁺⁾*Mo(CO)3(C₅(CH₂C₆H₅)5)^(1-) = Li[Mo(CO)3(C₅(CH₂C₆H₅)5)]

There total 1 articles about Li⁽¹⁺⁾*Mo(CO)3(C₅(CH₂C₆H₅)5)^(1-) = Li[Mo(CO)3(C₅(CH₂C₆H₅)5)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,2,3,4,5-pentabenzyl-1,3-cyclopentadiene (67209-29-4) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → Li(1+)*Mo(CO)3(C5(CH2C6H5)5)(1-) = Li[Mo(CO)3(C5(CH2C6H5)5)] (740801-07-4)

Guidance literature:

With n-BuLi; In tetrahydrofuran; hexane; (N2); addn. of n-BuLi in hexane at 0°C to C5Bz5 in THF, stirring (15 min), addn. of Mo(CO)6, reflux (ca. 24 h);

DOI:10.1016/0277-5387(96)00307-5

Reference yield: 76.0%

Li(1+)*Mo(CO)3(C5(CH2C6H5)5)(1-) = Li[Mo(CO)3(C5(CH2C6H5)5)] (740801-07-4) → [Mo(pentabenzylcyclopentadienyl)(CO)2]2

Guidance literature:

With CH₂CHCH₂Br; In tetrahydrofuran; under N2, Schlenk techniques; thf soln. of Mo compd. (2.57 mmol) treatedwith reagent (3.08 mmol), heated overnight at 50°C; evapd., extd. (Et2O), concd., crystd. (-20°C), elem. anal.;

DOI:10.1002/ejic.200600777

Reference yield: 5.0%

Li(1+)*Mo(CO)3(C5(CH2C6H5)5)(1-) = Li[Mo(CO)3(C5(CH2C6H5)5)] (740801-07-4) + phenylmercury(II) chloride (100-56-1) → (C5(CH2C6H5)5)(CO)3MoHgMo(CO)3(C5(CH2C6H5)5) + diphenylmercury(II) (587-85-9,1337-09-3)

Guidance literature:

In tetrahydrofuran; (N2); stirring (ca. 0°C, 1 h); solvent removal (reduced pressure), extn. (CH2Cl2), chromy. (SiO2; CH2Cl2/petroleum ether), recrystn. (CH2Cl2/petroleum ether); yield is for 2 steps; elem. anal.;

DOI:10.1016/0277-5387(96)00307-5

upstream raw materials:

1,2,3,4,5-pentabenzyl-1,3-cyclopentadiene

molybdenum hexacarbonyl

Downstream raw materials:

diphenylmercury(II)