Phenylmercury(1+);chloride

Base Information

• Chemical Name: Phenylmercury(1+);chloride
• CAS No.: 100-56-1
• Molecular Formula: C6H5 Cl Hg
• Molecular Weight: 313.149
• Hs Code.: 28439090
• UNII: X0R4ES0U7Z
• Mol file: 100-56-1.mol

Synonyms:phenylmercury(1+);chloride;PHENYLMERCURIC CHLORIDE [MI];PHENYLMERCURIC CHLORIDE [HSDB];PHENYL MERCURIC CHLORIDE [INCI];P0176;SR-01000864592;SR-01000864592-2

Chemical Property of Phenylmercury(1+);chloride

Chemical Property:

• Melting Point: 248-250 °C (dec.)(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.54820
• Storage Temp.: Poison room
• Water Solubility.: Soluble in benzene, ether, pyridine. Very slightly soluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 313.978621
• Heavy Atom Count: 8
• Complexity: 46.1

Purity/Quality:

98%min ^*data from raw suppliers

PhenylmercuricChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Toxic by ingestion, inhalation, and skin absorption.
• Hazard Codes: T+,N
• Statements: 26/27/28-33-50/53
• Safety Statements: 13-28-36-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Hg+].[Cl-]
• Uses: Phenylmercuric chloride has been used as an agricultural fungicide. The reaction of phenylmercury (II) chloride with acetophenonethiosemicarbazone (Hatsc) in ethanol in 1: 1 mole ratio undergoes symmetrisation forming the products, HgCl2 (Hatse) 2 and Ph2Hg instead of the anticipated compound PhHgCl (Hatse). A new method for the determination of chloride ion is based on the formation of phenylmercury(II) chloride, its extraction into chloroform and reaction with sodium diethyldithiocarbamate to form phenylmercury(II) diethyldithiocarbamate.

Technology Process of Phenylmercury(1+);chloride

There total 174 articles about Phenylmercury(1+);chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

phenyltrifluorosilane (368-47-8) → phenylmercury(II) chloride (100-56-1)

Guidance literature:

With mercury dichloride; In tetrahydrofuran; byproducts: ClSiF3; addn. of trifluorophenylsilane to a suspn. of HgCl2 in dry THF, reacting at 65°C for 0.5 h, pptn.;

DOI:10.1016/0022-328X(88)89077-6

Reference yield: 90.0%

mercury(II) diacetate (1600-27-7) + sodium chloride (7647-14-5) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → phenylmercury(II) chloride (100-56-1)

Guidance literature:

In water; N,N-dimethyl-formamide; other Radiation; microwave oven (2450 MHz, 1 min); evapn. (vac.), water addn., washing (water), drying, recrystn. (acetone);

DOI:10.1016/0277-5387(95)00569-2

Reference yield: 86.0%

(chloromethyl)trifluorosilane (1956-79-2) → phenylmercury(II) chloride (100-56-1)

Guidance literature:

With PhHgOCOCH₃; In tert-butyl alcohol; addn. of (chloromethyl)trifluorosilane to soln. of PhHgOCOCH3 in (CH3)3COH, (temp.: 100°C, 1 h);

DOI:10.1016/0022-328X(88)89077-6

upstream raw materials:

benzenediazonium

diphenyliodonium chloride

chloroformic acid ethyl ester

diphenylmercury(II)

Downstream raw materials:

dichloro-(4-phenoxy-phenyl)-phenyl-λ⁴-tellane

dibenzylmercury(II)

(1RS,2RS)-1-chloro-1,2-diphenyl-propane

1-acetoxy-3-phenylbut-2-ene

Refernces

• 1、 Dakternieks, Dainis,Dunn, Kerri,Schiesser, Carl H.,Tiekink, Edward R.T.. "Chiral organotin hydrides containing intramolecular coordinating substituents". . p. 209 - 220. Retrieved 2000.
• 2、 McClure,Lowy. "-". . p. 319. Retrieved 1931.
• 3、 Ayala, A. D.,Giagante, N.,Podesta, J. C.,Neumann, W. P.. "Organotin compounds X. Organotin hydride addition to methyl cyclohexene-1-carboxylate and methyl indene-3-carboxylate". . p. 317 - 330. Retrieved 1988.
• 4、 Poller,Toley. "-". . p. 453. Retrieved 1968.
• 5、 Nies, J. Dirk,Bellama, Jon M.,Ben-Zvi, Nava. "DIRECT TRANSFER OF ALIPHATIC AND AROMATIC SUBSTITUENTS FROM ORGANOSILATRANES TO MERCURY(II) SPECIES". . p. 315 - 320. Retrieved 1985.
• 6、 Booth, Brian L.,Casey, Geoffrey C.,Haszeldine, Robert N.. "Metal Carbonyl Chemistry. Part 27. Formation of by Reaction of the Carbene Precursor Hg(CCl3)Ph with Octacarbonyldicobalt". . p. 403 - 406. Retrieved 1980.
• 7、 Herwig, W.,Zeiss, H. H.. "". . p. 6561 - 6561. Retrieved 1957.
• 8、 Gun'kin, I. F.,Butin, K. P.,Beletskaya, I. P.,Reutov, O. A.. "". . . Retrieved 1981.
• 9、 Dakternieks, Dainis,Dunn, Kerri,Henry, David J.,Schiesser, Carl H.,Tiekink, Edward R. T.. "Organostannanes Derived from (-)-Menthol: Controlling Stereochemistry during the Preparation of (1R,2S,5R)-Menthyldiphenyltin Hydride and Bis((1R,2S,5R)-menthyl)phenyltin Hydride". . p. 3342 - 3347. Retrieved 1999.
• 10、 Waters. "-". . p. 2007,2013. Retrieved 1937.