(2S,5S)-2-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-5-methyl-cyclohexanone

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Chemical Name:(2S,5S)-2-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-5-methyl-cyclohexanone
CAS No.:220617-69-6
Molecular Formula:C₂₁H₃₂O₆
Molecular Weight:380.481
Hs Code.:

Synonyms:(2S,5S)-2-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-5-methyl-cyclohexanone

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Chemical Property of (2S,5S)-2-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-5-methyl-cyclohexanone

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Technology Process of (2S,5S)-2-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-5-methyl-cyclohexanone

There total 2 articles about (2S,5S)-2-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-5-methyl-cyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 103516-12-7
(Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose

: 220617-69-6
(2S,5S)-2-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-5-methyl-cyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) propanoic acid / 1.) 135 deg C, 3 h, 2.) toluene, 180 deg C, 20 h

2: 1.) CuBr*Me₂S, Me₂S / 1.) THF, -78 deg C, 15 min, 2.) THF, -78 deg C, 30 min

With copper(I) bromide dimethylsulfide complex; dimethylsulfide; propionic acid;
DOI:10.1016/S0957-4166(98)00465-0

Reference yield:

: 75-16-1
methylmagnesium bromide

: 220617-60-7
(S)-6-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-cyclohex-2-enone

: 220617-69-6
(2S,5S)-2-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-5-methyl-cyclohexanone

Guidance literature:: With copper(I) bromide dimethylsulfide complex; dimethylsulfide; Yield given. Multistep reaction; 1.) THF, -78 deg C, 15 min, 2.) THF, -78 deg C, 30 min;
DOI:10.1016/S0957-4166(98)00465-0