[(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane

Base Information

Chemical Name:[(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane
CAS No.:264626-94-0
Molecular Formula:C₂₁H₃₂N₆O₅SSi
Molecular Weight:508.674
Hs Code.:

[(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane

Synonyms:[(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane

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Chemical Property of [(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane

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Technology Process of [(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane

There total 1 articles about [(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 264626-91-7
phenyl (3-azido-2,3-dideoxy-4-trimethylsilyl-α-L-fucopyranosyl)-(1-4)-3-azido-2,3-dideoxy-1-thio-α-L-fucopyranoside

: 264626-94-0
[(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -42 - -20 ℃;
DOI:10.1021/ja992513f

Reference yield: 74.0%

: 264626-94-0
[(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane

: 264626-93-9
phenyl [[(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-3-azido-2,3-dideoxy-1-thio-α-L-fucopyranoside

: 264626-95-1
phenyl [[[[(3-azido-2,3-dideoxy-4-trimethylsilyl-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-(3-azido-2,3-dideoxy-α-L-fucopyranosyl)]-(1-4)-3-azido-2,3-dideoxy-1-thio-α-...

Guidance literature:: With trifluoromethylsulfonic anhydride; 4 A molecular sieve; In diethyl ether; dichloromethane; at -78 ℃; for 0.25h;
DOI:10.1021/ja992513f

Reference yield:

: 264626-94-0
[(2S,3S,4S,6S)-4-Azido-6-((2S,3S,4S,6S)-4-azido-6-benzenesulfinyl-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-trimethyl-silane

: 264626-97-3
C₃₇H₅₃N₁₅O₁₀S

Guidance literature:: Multi-step reaction with 3 steps

1.1: 74 percent / triflic anhydride; 4 Angstroem molecular sieves / CH₂Cl₂; diethyl ether / 0.25 h / -78 °C

2.1: 90 percent / pyridinium hydrofluoride / tetrahydrofuran / 1 h

3.1: NaH / dimethylformamide / 0.08 h

3.2: 97 percent / dimethylformamide / 0.33 h

With trifluoromethylsulfonic anhydride; 4 A molecular sieve; sodium hydride; pyridine hydrogenfluoride; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide; 1.1: Condensation / 2.1: desilylation / 3.1: Metallation / 3.2: Methylation;
DOI:10.1021/ja992513f