chloro(bis(5-H-dibenzo[a,d]cyclohepten-5-yl)amine)(triphenylphosphine)rhodium(I)

Base Information

Chemical Name:chloro(bis(5-H-dibenzo[a,d]cyclohepten-5-yl)amine)(triphenylphosphine)rhodium(I)
CAS No.:871737-25-6
Molecular Formula:C₄₈H₃₈ClNPRh
Molecular Weight:798.169
Hs Code.:

Synonyms:chloro(bis(5-H-dibenzo[a,d]cyclohepten-5-yl)amine)(triphenylphosphine)rhodium(I)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of chloro(bis(5-H-dibenzo[a,d]cyclohepten-5-yl)amine)(triphenylphosphine)rhodium(I)

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Technology Process of chloro(bis(5-H-dibenzo[a,d]cyclohepten-5-yl)amine)(triphenylphosphine)rhodium(I)

There total 1 articles about chloro(bis(5-H-dibenzo[a,d]cyclohepten-5-yl)amine)(triphenylphosphine)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: di-μ-chlorobis[(bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine)rhodium(I)]

: 603-35-0
triphenylphosphine

: 871737-25-6
(bis(5H-dibenzo[a,d]cyclohepten-5-yl)amine)chloro(triphenylphosphine)rhodium(I)

Guidance literature:: In tetrahydrofuran; at 60 ℃;

Reference yield: 80.0%

: 871737-25-6
chloro(bis(5-H-dibenzo[a,d]cyclohepten-5-yl)amine)(triphenylphosphine)rhodium(I)

: 871737-27-8
(bis(5-H-dibenzo[a,d]cyclohepten-5-yl)amide)(triphenylphosphine)rhodium(I)

Guidance literature:: With KOC(CH₃)3; In tetrahydrofuran; toluene; under exclusion of moisture and oxygen to Rh-complex one equiv. of KOC(CH3)3 in THF added, 50 vol% of toluene added; volatiles removed (vac.), residue extracted with THF, filtered, concd., extract layered with 1/1/10 THF/toluene/n-hexane mixt.;
DOI:10.1002/anie.200500773