Acetic acid (2S,5R,6S)-5-(2,4-dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

Base Information

• Chemical Name: Acetic acid (2S,5R,6S)-5-(2,4-dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester
• CAS No.: 171555-23-0
• Molecular Formula: C₁₅H₁₉N₃O₈
• Molecular Weight: 369.331
• Mol file: 171555-23-0.mol

Synonyms:Acetic acid (2S,5R,6S)-5-(2,4-dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

Chemical Property of Acetic acid (2S,5R,6S)-5-(2,4-dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of Acetic acid (2S,5R,6S)-5-(2,4-dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester

There total 1 articles about Acetic acid (2S,5R,6S)-5-(2,4-dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

2,4-Dinitrofluorobenzene (70-34-8,65727-75-5) + methyl 6-O-acetyl-2-amino-2,3,4-trideoxy-α-D-erythro-hexopyranoside (171555-22-9) → Acetic acid (2S,5R,6S)-5-(2,4-dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester (171555-23-0)

Guidance literature:

With sodium hydrogencarbonate; In water; acetone;

DOI:10.1016/0040-4039(95)01293-Q

Reference yield: 100.0%

Acetic acid (2S,5R,6S)-5-(2,4-dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester (171555-23-0) → [(2S,5R,6S)-5-(2,4-Dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-yl]-methanol

Guidance literature:

With potassium carbonate; In methanol;

DOI:10.1016/0040-4039(95)01293-Q

Reference yield:

acetic anhydride (108-24-7) + Acetic acid (2S,5R,6S)-5-(2,4-dinitro-phenylamino)-6-methoxy-tetrahydro-pyran-2-ylmethyl ester (171555-23-0) → Acetic acid (2S,3R,6S)-6-acetoxymethyl-3-(2,4-dinitro-phenylamino)-tetrahydro-pyran-2-yl ester + Acetic acid (2R,3R,6S)-6-acetoxymethyl-3-(2,4-dinitro-phenylamino)-tetrahydro-pyran-2-yl ester

Guidance literature:

With sulfuric acid; In dichloromethane; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1016/0040-4039(95)01293-Q

upstream raw materials:

2,4-Dinitrofluorobenzene

methyl 6-O-acetyl-2-amino-2,3,4-trideoxy-α-D-erythro-hexopyranoside