(3S,4R,5R,6R)-4,5,6-tris(benzyloxy)-3-hydroxyazepane-1-carboxylic acid benzyl ester

Base Information

Chemical Name:(3S,4R,5R,6R)-4,5,6-tris(benzyloxy)-3-hydroxyazepane-1-carboxylic acid benzyl ester
CAS No.:1187433-18-6
Molecular Formula:C₃₅H₃₇NO₆
Molecular Weight:567.682
Hs Code.:

Synonyms:(3S,4R,5R,6R)-4,5,6-tris(benzyloxy)-3-hydroxyazepane-1-carboxylic acid benzyl ester

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Chemical Property of (3S,4R,5R,6R)-4,5,6-tris(benzyloxy)-3-hydroxyazepane-1-carboxylic acid benzyl ester

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Technology Process of (3S,4R,5R,6R)-4,5,6-tris(benzyloxy)-3-hydroxyazepane-1-carboxylic acid benzyl ester

There total 3 articles about (3S,4R,5R,6R)-4,5,6-tris(benzyloxy)-3-hydroxyazepane-1-carboxylic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1206474-43-2
C₄₂H₄₁NO₇

: 1187433-18-6
(3S,4R,5R,6R)-4,5,6-tris(benzyloxy)-3-hydroxyazepane-1-carboxylic acid benzyl ester

Guidance literature:: C₄₂H₄₁NO₇; With sodium methylate; In methanol; at 20 - 40 ℃; pH=9 - 10;

In methanol; for 0.5h;
DOI:10.1016/j.bmc.2009.06.022

Reference yield: 83.0%

: C₄₂H₄₂N₂O₈

: 1187433-18-6
(3S,4R,5R,6R)-4,5,6-tris(benzyloxy)-3-hydroxyazepane-1-carboxylic acid benzyl ester

Guidance literature:: With methanol; potassium carbonate; In tetrahydrofuran; at 20 ℃; for 5h;
DOI:10.1039/c4ob00325j

Reference yield:

: 924895-17-0
(3S,4R,5R,6R)-benzyl 3,4,5-tris(benzyloxy)-6-hydroxyazepane-1-carboxylate

: 1187433-18-6
(3S,4R,5R,6R)-4,5,6-tris(benzyloxy)-3-hydroxyazepane-1-carboxylic acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: diethylazodicarboxylate; triphenylphosphine / tetrahydrofuran; toluene / 3 h / 0 - 20 °C

2: methanol; potassium carbonate / tetrahydrofuran / 5 h / 20 °C

With methanol; potassium carbonate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; toluene; 1: |Mitsunobu Displacement;
DOI:10.1039/c4ob00325j