methyl 6-O-benzoyl-3-O-dimethoxyphosphoryl-4-C-[(E)-(methoxycarbonyl)methylene]-2,4-dideoxy-α-D-glycero-hex-2-enopyranoside

Base Information

Chemical Name:methyl 6-O-benzoyl-3-O-dimethoxyphosphoryl-4-C-[(E)-(methoxycarbonyl)methylene]-2,4-dideoxy-α-D-glycero-hex-2-enopyranoside
CAS No.:191729-46-1
Molecular Formula:C₁₉H₂₃O₁₀P
Molecular Weight:442.359
Hs Code.:

Synonyms:methyl 6-O-benzoyl-3-O-dimethoxyphosphoryl-4-C-[(E)-(methoxycarbonyl)methylene]-2,4-dideoxy-α-D-glycero-hex-2-enopyranoside

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Chemical Property of methyl 6-O-benzoyl-3-O-dimethoxyphosphoryl-4-C-[(E)-(methoxycarbonyl)methylene]-2,4-dideoxy-α-D-glycero-hex-2-enopyranoside

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Technology Process of methyl 6-O-benzoyl-3-O-dimethoxyphosphoryl-4-C-[(E)-(methoxycarbonyl)methylene]-2,4-dideoxy-α-D-glycero-hex-2-enopyranoside

There total 2 articles about methyl 6-O-benzoyl-3-O-dimethoxyphosphoryl-4-C-[(E)-(methoxycarbonyl)methylene]-2,4-dideoxy-α-D-glycero-hex-2-enopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 25552-06-1
((2R,6S)-4-(benzoyloxy)-6-methoxy-3-oxo-3,6-dihydro-2H-pyran-2-yl)methyl benzoate

: 5927-18-4
trimethyl phosphonoacetate

: 191729-46-1
methyl 6-O-benzoyl-3-O-dimethoxyphosphoryl-4-C-[(E)-(methoxycarbonyl)methylene]-2,4-dideoxy-α-D-glycero-hex-2-enopyranoside

Guidance literature:: trimethyl phosphonoacetate; With sodium hydride; In 1,2-dimethoxyethane; at 0 ℃; for 0.75h;

((2R,6S)-4-(benzoyloxy)-6-methoxy-3-oxo-3,6-dihydro-2H-pyran-2-yl)methyl benzoate; In 1,2-dimethoxyethane; for 0.5h;
DOI:10.1080/07328309908544032

Reference yield: 47.0%

: 25552-06-1
((2R,6S)-4-(benzoyloxy)-6-methoxy-3-oxo-3,6-dihydro-2H-pyran-2-yl)methyl benzoate

: 5927-18-4
trimethyl phosphonoacetate

: 191729-46-1
methyl 6-O-benzoyl-3-O-dimethoxyphosphoryl-4-C-[(E)-(methoxycarbonyl)methylene]-2,4-dideoxy-α-D-glycero-hex-2-enopyranoside

: methyl 4,6-di-O-benzoyl-2-deoxy-2-C-[(methoxycarbonyl)methyl]-3-O-dimethoxyphosphoryl-α-D-threo-hex-3-enopyranoside

Guidance literature:: trimethyl phosphonoacetate; With sodium hydride; In toluene; at 0 ℃; for 0.75h;

((2R,6S)-4-(benzoyloxy)-6-methoxy-3-oxo-3,6-dihydro-2H-pyran-2-yl)methyl benzoate; In toluene; for 0.5h;
DOI:10.1080/07328309908544032

Reference yield: 80.0%

: 191729-46-1
methyl 6-O-benzoyl-3-O-dimethoxyphosphoryl-4-C-[(E)-(methoxycarbonyl)methylene]-2,4-dideoxy-α-D-glycero-hex-2-enopyranoside

: methyl 6-O-benzoyl-2,4-dideoxy-4-C-<(methoxycarbonyl)methyl>-3-O-(dimethoxyphosphoryl)-α-D-glycero-hex-3-enopyranoside

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; for 4h; under 32065.1 Torr; Ambient temperature;
DOI:10.1080/07328309908543975