(2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal

Base Information

Chemical Name:(2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal
CAS No.:162020-79-3
Molecular Formula:C₂₂H₄₀O₃Si₂
Molecular Weight:408.729
Hs Code.:

Synonyms:(2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal

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Chemical Property of (2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal

Chemical Property:

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Technology Process of (2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal

There total 6 articles about (2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 162020-87-3
(2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanoic acid methoxy-methyl-amide

: 162020-79-3
(2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; at 0 ℃;
DOI:10.1016/0040-4039(94)02416-9

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 162020-79-3
(2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal

Guidance literature:: Multi-step reaction with 6 steps

1: 2,6-lutidine

2: O₃, dimethyl sulfide

3: 75 percent / Bu₂BOTf, iPr₂NEt

4: 97 percent / AlMe₃

5: 90 percent / Et₃N

6: 73 percent / DIBAL / tetrahydrofuran / 0 °C

With 2,6-dimethylpyridine; dimethylsulfide; di-n-butylboryl trifluoromethanesulfonate; trimethylaluminum; diisobutylaluminium hydride; ozone; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran;
DOI:10.1016/0040-4039(94)02416-9

Reference yield:

: 87184-81-4
4-(tert-butyldimethylsilanyloxy)butanal

: 162020-79-3
(2S,3R)-2-Benzyl-6-(tert-butyl-dimethyl-silanyloxy)-3-trimethylsilanyloxy-hexanal

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / Bu₂BOTf, iPr₂NEt

2: 97 percent / AlMe₃

3: 90 percent / Et₃N

4: 73 percent / DIBAL / tetrahydrofuran / 0 °C

With di-n-butylboryl trifluoromethanesulfonate; trimethylaluminum; diisobutylaluminium hydride; triethylamine; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran;
DOI:10.1016/0040-4039(94)02416-9