{(R)-1-[(E)-(S)-2-(2-Bromo-1-ethoxy-ethoxy)-non-3-enyl]-dodecyloxymethyl}-benzene

Base Information

Chemical Name:{(R)-1-[(E)-(S)-2-(2-Bromo-1-ethoxy-ethoxy)-non-3-enyl]-dodecyloxymethyl}-benzene
CAS No.:902769-98-6
Molecular Formula:C₃₂H₅₅BrO₃
Molecular Weight:567.691
Hs Code.:

Synonyms:{(R)-1-[(E)-(S)-2-(2-Bromo-1-ethoxy-ethoxy)-non-3-enyl]-dodecyloxymethyl}-benzene

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Chemical Property of {(R)-1-[(E)-(S)-2-(2-Bromo-1-ethoxy-ethoxy)-non-3-enyl]-dodecyloxymethyl}-benzene

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Technology Process of {(R)-1-[(E)-(S)-2-(2-Bromo-1-ethoxy-ethoxy)-non-3-enyl]-dodecyloxymethyl}-benzene

There total 12 articles about {(R)-1-[(E)-(S)-2-(2-Bromo-1-ethoxy-ethoxy)-non-3-enyl]-dodecyloxymethyl}-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 902769-93-1
(E)-(8S,10R)-10-Benzyloxy-henicos-6-en-8-ol

: 109-92-2,25104-37-4
ethyl vinyl ether

: 902769-98-6
{(R)-1-[(E)-(S)-2-(2-Bromo-1-ethoxy-ethoxy)-non-3-enyl]-dodecyloxymethyl}-benzene

Guidance literature:: With N-Bromosuccinimide; In dichloromethane; at 0 - 20 ℃; for 4h;
DOI:10.1016/j.tetlet.2006.04.101

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 902769-98-6
{(R)-1-[(E)-(S)-2-(2-Bromo-1-ethoxy-ethoxy)-non-3-enyl]-dodecyloxymethyl}-benzene

Guidance literature:: Multi-step reaction with 6 steps

1: 79 percent / PTSA / CH₂Cl₂ / 0 - 20 °C

2: 69 percent / DIBAL-H / CH₂Cl₂ / -78 °C

3: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 °C

4: tetrahydrofuran / 0 - 20 °C

5: 85 percent / LiAlH₄ / tetrahydrofuran / 0 - 20 °C

6: 90 percent / NBS / CH₂Cl₂ / 4 h / 0 - 20 °C

With N-Bromosuccinimide; lithium aluminium tetrahydride; oxalyl dichloride; diisobutylaluminium hydride; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; dichloromethane; 3: Swern oxidation;
DOI:10.1016/j.tetlet.2006.04.101

Reference yield:

: 17049-50-2
n-decyl magnesium bromide

: 902769-98-6
{(R)-1-[(E)-(S)-2-(2-Bromo-1-ethoxy-ethoxy)-non-3-enyl]-dodecyloxymethyl}-benzene

Guidance literature:: Multi-step reaction with 6 steps

1: CuBr / tetrahydrofuran / 4 h / 0 - 20 °C

2: 69 percent / DIBAL-H / CH₂Cl₂ / -78 °C

3: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 °C

4: tetrahydrofuran / 0 - 20 °C

5: 85 percent / LiAlH₄ / tetrahydrofuran / 0 - 20 °C

6: 90 percent / NBS / CH₂Cl₂ / 4 h / 0 - 20 °C

With N-Bromosuccinimide; lithium aluminium tetrahydride; oxalyl dichloride; diisobutylaluminium hydride; dimethyl sulfoxide; triethylamine; copper(I) bromide; In tetrahydrofuran; dichloromethane; 3: Swern oxidation;
DOI:10.1016/j.tetlet.2006.04.101