(1R,2S)-1-{[4-(methyloxy)phenyl]carbonyl}-2-(4-nitrophenyl)cyclopropanecarbonitrile

Base Information

Chemical Name:(1R,2S)-1-{[4-(methyloxy)phenyl]carbonyl}-2-(4-nitrophenyl)cyclopropanecarbonitrile
CAS No.:1309588-33-7
Molecular Formula:C₁₈H₁₄N₂O₄
Molecular Weight:322.32
Hs Code.:

Synonyms:(1R,2S)-1-{[4-(methyloxy)phenyl]carbonyl}-2-(4-nitrophenyl)cyclopropanecarbonitrile

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Chemical Property of (1R,2S)-1-{[4-(methyloxy)phenyl]carbonyl}-2-(4-nitrophenyl)cyclopropanecarbonitrile

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Technology Process of (1R,2S)-1-{[4-(methyloxy)phenyl]carbonyl}-2-(4-nitrophenyl)cyclopropanecarbonitrile

There total 2 articles about (1R,2S)-1-{[4-(methyloxy)phenyl]carbonyl}-2-(4-nitrophenyl)cyclopropanecarbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 100-13-0
4-nitrostyrene

: 126893-72-9
2-(4-methoxyphenyl)-2-oxoethanecarbonimidoyl cyanide

: 1309588-33-7
(1R,2S)-1-{[4-(methyloxy)phenyl]carbonyl}-2-(4-nitrophenyl)cyclopropanecarbonitrile

Guidance literature:: With tetrakis[(S)-(N-tetrachlorophthalimido)-tert-lucinato]dirhodium(II); In diethyl ether; at -35 ℃; for 16h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja201237j

Reference yield:

: 3672-47-7
3-oxo-3-(4'-methoxyphenyl)propanenitrile

: 1309588-33-7
(1R,2S)-1-{[4-(methyloxy)phenyl]carbonyl}-2-(4-nitrophenyl)cyclopropanecarbonitrile

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine; triflic azide / hexane; acetonitrile / 16 h / 0 - 20 °C / Inert atmosphere

2: tetrakis[(S)-(N-tetrachlorophthalimido)-tert-lucinato]dirhodium(II) / diethyl ether / 16 h / -35 °C / Inert atmosphere

With pyridine; tetrakis[(S)-(N-tetrachlorophthalimido)-tert-lucinato]dirhodium(II); triflic azide; In diethyl ether; hexane; acetonitrile;
DOI:10.1021/ja201237j