Ni(bis(1-methyl-2-imidazolyl)methylphenylborate)2*THF

Base Information

• Chemical Name: Ni(bis(1-methyl-2-imidazolyl)methylphenylborate)2*THF
• CAS No.: 1263104-24-0
• Molecular Formula: C₄H₈O*C₃₀H₃₆B₂N₈Ni
• Molecular Weight: 661.088
• Mol file: 1263104-24-0.mol

Synonyms:

Chemical Property of Ni(bis(1-methyl-2-imidazolyl)methylphenylborate)2*THF

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ni(bis(1-methyl-2-imidazolyl)methylphenylborate)2*THF

There total 1 articles about Ni(bis(1-methyl-2-imidazolyl)methylphenylborate)2*THF which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + chlorotris(triphenylphosphine)nickel (15169-64-9) + H[MePhB(Im(N-Me))2] (279221-32-8) → Ni(bis(1-methyl-2-imidazolyl)methylphenylborate)2*THF (1263104-24-0)

Guidance literature:

In methanol; toluene; Schlenk techniques used under Ar, toluene soln. of H(B(Im-N-Me)2(Me)Ph) (0.64 mmol) slowly added to methanol soln. of Ni(OAc)2*4H2O (0.65 mmol),stirred overnight, settled for 1 h; decanted, dried under vac., recrystallizated from CH3CN/THF; XRD;

DOI:10.1002/ejic.201000629

upstream raw materials:

tetrahydrofuran

chlorotris(triphenylphosphine)nickel

H[MePhB(Im(N-Me))2]