TRIBUTYL(PHENYLETHENYL)TIN

Base Information

• Chemical Name: TRIBUTYL(PHENYLETHENYL)TIN
• CAS No.: 79159-76-5
• Molecular Formula: C₂₀H₃₄Sn
• Molecular Weight: 393.2
• Mol file: 79159-76-5.mol

Synonyms:(E)-Tributyl(2-phenylethenyl)stannane;1-Phenyl-2-(tributylstannyl)ethylene; Styryltributylstannane;Tributyl(styryl)stannane; b-Tributylstannylstyrene

Chemical Property of TRIBUTYL(PHENYLETHENYL)TIN

Chemical Property:

• Boiling Point: 404.7±38.0 °C(Predicted)
• PSA: 0.00000
• LogP: 7.08810

Purity/Quality:

96% ^*data from raw suppliers

Tributyl(phenylethenyl)tin ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIBUTYL(PHENYLETHENYL)TIN

There total 27 articles about TRIBUTYL(PHENYLETHENYL)TIN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tri-n-butyl-tin hydride (688-73-3) + phenylacetylene (536-74-3) → (E)-1-phenyl-(2-tributylstannyl)ethene (66680-87-3,66680-88-4,79159-76-5)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); oxygen; In benzene-d6; at 80 ℃; for 2h; diastereoselective reaction;

DOI:10.1002/anie.201303736

Reference yield: 98.0%

tri-n-butyl-tin hydride (688-73-3) + C36H47FeOP → (E)-1-phenyl-(2-tributylstannyl)ethene (66680-87-3,66680-88-4,79159-76-5) + Cp*Fe(1,2-PCy2C6H4O)

Guidance literature:

In toluene; at 20 ℃; Inert atmosphere;

DOI:10.1021/jacs.0c11448

Reference yield: 97.0%

tri-n-butyl-tin hydride (688-73-3) + Cp*Fe(1,2-PCy2C6H4O) + phenylacetylene (536-74-3) → (E)-1-phenyl-(2-tributylstannyl)ethene (66680-87-3,66680-88-4,79159-76-5)

Guidance literature:

Cp*Fe(1,2-PCy₂C₆H₄O); phenylacetylene; In toluene; at 20 ℃; for 0.0833333h; Inert atmosphere;

tri-n-butyl-tin hydride; In toluene; at 20 ℃; for 12h; Reagent/catalyst; regioselective reaction; Inert atmosphere;

DOI:10.1021/jacs.0c11448

upstream raw materials:

(tri(n-butyl)stannyl)dimethylsilane

phenylacetylene

tri-n-butyl-tin hydride

tri-n-butyltin lithium

Downstream raw materials:

(E)-(HOCH₂)(CH₃)C(CHCH₂)CHCHPh

(Z,E)-2-methyl-6-phenylhexa-2,5-dien-1-ol

(E,E)-(CH₃)(HOCH₂)CCHCH₂CHCHPh

3,3,3-trichloro-1-phenyl-propene

Refernces

• 1、 Sakamoto, Kyoka,Nagashima, Yuki,Wang, Chao,Miyamoto, Kazunori,Tanaka, Ken,Uchiyama, Masanobu. "Illuminating Stannylation". supporting information. p. 5629 - 5635. Retrieved 2021/05/04.
• 2、 Magre, Marc,Szewczyk, Marcin,Rueping, Magnus. "Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes". supporting information. p. 1594 - 1598. Retrieved 2020/02/22.