dichloro[propane-1,3-diylbis(diphenylphosphane)]nickel(II)

Base Information

• Chemical Name: dichloro[propane-1,3-diylbis(diphenylphosphane)]nickel(II)
• CAS No.: 55659-60-4
• Molecular Formula: C₂₇H₂₆Cl₂NiP₂
• Molecular Weight: 542.047
• Mol file: 55659-60-4.mol

Synonyms:dichloro[propane-1,3-diylbis(diphenylphosphane)]nickel(II)

Chemical Property of dichloro[propane-1,3-diylbis(diphenylphosphane)]nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro[propane-1,3-diylbis(diphenylphosphane)]nickel(II)

There total 6 articles about dichloro[propane-1,3-diylbis(diphenylphosphane)]nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

nickel(II) chloride hexahydrate + 1,3-bis-(diphenylphosphino)propane (6737-42-4) → 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) (55659-61-5,15629-92-2,55659-60-4)

Guidance literature:

In methanol; isopropyl alcohol; at 60 ℃;

DOI:10.1080/00958972.2020.1837784

Reference yield:

1,3-bis-(diphenylphosphino)propane (6737-42-4) + nickel dichloride (83864-14-6) → 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) (55659-61-5,15629-92-2,55659-60-4)

Guidance literature:

In not given;

DOI:10.1021/ja0103492

Reference yield:

nickel(II) chloride hexahydrate → 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) (55659-61-5,15629-92-2,55659-60-4)

Guidance literature:

With DPPP; In ethanol; the warm soln. of Ni salt and ligand under inert gas; the soln. was filtered, ppt. was washed with heptane, ether, dried in vac.;

upstream raw materials:

1,3-bis-(diphenylphosphino)propane

nickel dichloride

Downstream raw materials:

5,5′-diphenyl-2,2′-bithiophene

2,2'-Bithiophene

2-(4-fluorophenylmethyl)thiophene

methyl 3-methoxy-6-methylpyrazine-2-carboxylate