Ru₃(CO)11(P(C₆H₅)2(C₅H₄N))

Base Information

Chemical Name:Ru₃(CO)11(P(C₆H₅)2(C₅H₄N))
CAS No.:99593-33-6
Molecular Formula:C₂₈H₁₄NO₁₁PRu₃
Molecular Weight:874.603
Hs Code.:

Ru<sub>3</sub>(CO)11(P(C<sub>6</sub>H<sub>5</sub>)2(C<sub>5</sub>H<sub>4</sub>N))

Synonyms:Ru₃(CO)11(P(C₆H₅)2(C₅H₄N))

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Chemical Property of Ru₃(CO)11(P(C₆H₅)2(C₅H₄N))

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Technology Process of Ru₃(CO)11(P(C₆H₅)2(C₅H₄N))

There total 1 articles about Ru₃(CO)11(P(C₆H₅)2(C₅H₄N)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 37943-90-1
2-(diphenylphosphino)pyridine

: 99593-33-6
Ru₃(CO)11(P(C₆H₅)2(C₅H₄N))

Guidance literature:: With catalyst: {(C₆H₅)3PNP(C₆H₅)3}CN; In tetrahydrofuran; all manipulations under N2; stirring a soln. of Ru3(CO)12 and the ligand in THF (25°C), adding bis (triphenylphosphoranylidene)ammonium cyanate dissolved in the min. amt. of CH2Cl2, color change from orange to red, gas evolution, evapg. (vac.); monitored by IR (quantitative formation within 2 min); partial decompn. on removal of THF under vac. (traces of Ru3(C(O)(C6H5))(P(C6H5)(C5H4N))(CO)9 are detected by NMR);
DOI:10.1021/ic00251a019

Reference yield: 90.0%

: 99593-33-6
Ru₃(CO)11(P(C₆H₅)2(C₅H₄N))

: {Ru₃(C₆H₅CO)(P(C₆H₅)(C₅H₄N))(CO)9}

Guidance literature:: In tetrahydrofuran; standing in THF soln. under an inert atmosphere at 25°C (48 h) or at 40°C (2 h); elem. anal.;
DOI:10.1021/ic00251a019

Reference yield: 85.0%

: 99593-33-6
Ru₃(CO)11(P(C₆H₅)2(C₅H₄N))

: 99641-43-7
Ru3(μ-C(O)(C6H5))(μ3-P(C6H5)(C5H4N))(CO)9

Guidance literature:: In tetrahydrofuran; react. at 40°C in THF for 2 h; chromy. on silica gel and elution with CH2Cl2-petroleum ether; elem. anal.;