2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside

Base Information

Chemical Name:2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside
CAS No.:653597-42-3
Molecular Formula:C₃₇H₄₁N₃O₇
Molecular Weight:639.748
Hs Code.:

Synonyms:2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside

Suppliers and Price of 2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside

There total 4 articles about 2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 100-39-0
benzyl bromide

: 653597-41-2
2-azidoethyl 3-O-(p-methoxybenzyl)-α-D-mannopyranoside

: 653597-42-3
2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃;
DOI:10.1081/CAR-120026459

Reference yield:

: 140428-83-7
2-azidoethyl 2,3,4,6-tetra-O-acetyl-α-D-mannopyranoside

: 653597-42-3
2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1.1: 99 percent / NaOMe / methanol / 20 °C

2.1: 707 mg / p-TsOH / acetonitrile / 60 °C

3.1: Bu₂SnO / methanol / 1 h / Heating

3.2: 612 mg / CsF / dimethylformamide / 20 °C

4.1: 85 percent / acetic acid / 3 h / 70 °C

5.1: 88 percent / NaH / dimethylformamide / 0 - 20 °C

With sodium methylate; sodium hydride; di(n-butyl)tin oxide; toluene-4-sulfonic acid; acetic acid; In methanol; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1081/CAR-120026459

Reference yield:

: 653597-39-8
2-azidoethyl 4,6-O-benzylidene-α-D-mannopyranoside

: 653597-42-3
2-azidoethyl 2,4,6-tri-O-benzyl-3-O-(p-methoxybenzyl)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: Bu₂SnO / methanol / 1 h / Heating

1.2: 612 mg / CsF / dimethylformamide / 20 °C

2.1: 85 percent / acetic acid / 3 h / 70 °C

3.1: 88 percent / NaH / dimethylformamide / 0 - 20 °C

With sodium hydride; di(n-butyl)tin oxide; acetic acid; In methanol; N,N-dimethyl-formamide;
DOI:10.1081/CAR-120026459