1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol

Base Information

Chemical Name:1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol
CAS No.:102997-56-8
Molecular Formula:C₂₇H₂₆O₅
Molecular Weight:430.5
Hs Code.:

Synonyms:1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol

Suppliers and Price of 1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol

There total 1 articles about 1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 85798-11-4
(4S,5R,6S)-4,5,6-tris-benzyloxycyclohex-2-en-1-one

: 102997-56-8
1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol

Guidance literature:: With tert.-butylhydroperoxide; N-benzyl-trimethylammonium hydroxide; In dichloromethane; for 1h; Ambient temperature;
DOI:10.1055/s-1997-1292

Reference yield:

: 102997-56-8
1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol

: Acetic acid (1S,2R,3S,4S,5S,6R)-3-azido-4,5,6-tris-benzyloxy-2-hydroxy-cyclohexylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) BuLi / 1.) THF, hexane, 2.) THF, hexane, RT, 15 min

2: 1.) B₂H₆, 2.) 2 N aq. NaOH, 30percent aq. H₂O₂ / 1.) THF, 2.) THF, RT, 30 min

3: pyridine

4: NaN₃, aq. NH₄Cl / 2-methoxy-ethanol / 16 h / 80 °C

With pyridine; sodium hydroxide; n-butyllithium; sodium azide; dihydrogen peroxide; ammonium chloride; diborane; In 2-methoxy-ethanol;
DOI:10.1055/s-1997-1292

Reference yield:

: 102997-56-8
1R(1,2,4/3,5)-1,2-anhydro-3,4,5-tri-O-benzyl-6-enecyclohexane-1,2,3,4,5-pentol

: 157761-58-5
((1R,2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-7-oxabicyclo-[4.1.0]heptan-2-yl)methanol (+)-2,3,4-tri-O-benzylcyclophellitol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) BuLi / 1.) THF, hexane, 2.) THF, hexane, RT, 15 min

2: 1.) B₂H₆, 2.) 2 N aq. NaOH, 30percent aq. H₂O₂ / 1.) THF, 2.) THF, RT, 30 min

With sodium hydroxide; n-butyllithium; dihydrogen peroxide; diborane;
DOI:10.1055/s-1997-1292