trans-hex-2-enyl 4-chlorophenyl carbonate

Base Information

• Chemical Name: trans-hex-2-enyl 4-chlorophenyl carbonate
• CAS No.: 1419028-40-2
• Molecular Formula: C₁₃H₁₅ClO₃
• Molecular Weight: 254.713
• Mol file: 1419028-40-2.mol

Synonyms:trans-hex-2-enyl 4-chlorophenyl carbonate

Chemical Property of trans-hex-2-enyl 4-chlorophenyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-hex-2-enyl 4-chlorophenyl carbonate

There total 1 articles about trans-hex-2-enyl 4-chlorophenyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(E)-2-Hexen-1-ol (928-95-0) + 4-Chlorophenyl chloroformate (7693-45-0) → trans-hex-2-enyl 4-chlorophenyl carbonate (1419028-40-2)

Guidance literature:

With N,N,N,N,-tetramethylethylenediamine; triethylamine; In dichloromethane; at 0 - 20 ℃; for 0.5h;

DOI:10.1021/ol3033237

Reference yield:

trans-hex-2-enyl 4-chlorophenyl carbonate (1419028-40-2) → (S)-(+)-3-(4-chlorophenoxy)hexa-1-ene + (R)-1-chloro-4-(hex-1-en-3-yloxy)benzene + 1-Chloro-4-[((E)-hex-2-enyl)oxy]-benzene

Guidance literature:

With bis(1,5-cyclooctadiene)diiridium(I) dichloride; [O,O'-(S)-(1,1'-dinaphthyl-2,2'-diyl)-N,N’-di-(S,S)-1-(2-methoxyphenyl)ethylphosphoramidite]; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 20 ℃; enantioselective reaction; Inert atmosphere;

DOI:10.1021/ol3033237

upstream raw materials:

(E)-2-Hexen-1-ol

4-Chlorophenyl chloroformate