Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane

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Chemical Name:Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane
CAS No.:188014-78-0
Molecular Formula:C₃₆H₅₄O₅Si
Molecular Weight:594.907
Hs Code.:

Synonyms:Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane

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Chemical Property of Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane

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Technology Process of Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane

There total 7 articles about Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 107-30-2
chloromethyl methyl ether

: 188014-77-9
(Z)-3-(4-Methoxy-benzyloxymethyl)-1-[5-methyl-2-(2-methyl-1-triisopropylsilanyloxy-allyl)-phenyl]-penta-2,4-dien-1-ol

: 188014-78-0
Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane

Guidance literature:: With N,N-diethyl-N-isopropylamine; In dichloromethane;
DOI:10.1016/S0040-4039(96)02459-8

Reference yield:

: 587-03-1
3-methylbenzyl alcohol

: 188014-78-0
Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) n-BuLi, TMEDA / 1.) pentane; 2.) pentane, -78 deg C,

2: 78 percent / imidazole / CH₂Cl₂ / 21 °C

3: 97 percent / collidine / CH₂Cl₂ / 21 °C

4: 89 percent / PPTS / aq. ethanol / 21 °C

5: 89 percent / CH₂Cl₂ / 21 °C / Dess-Martin ox.

6: 86 percent / tetrahydrofuran / -78 °C

7: 97 percent / i-PrEt₂N / CH₂Cl₂

With 1H-imidazole; 2,3,5-trimethyl-pyridine; n-butyllithium; N,N-diethyl-N-isopropylamine; N,N,N,N,-tetramethylethylenediamine; pyridinium p-toluenesulfonate; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1016/S0040-4039(96)02459-8

Reference yield:

: 188014-75-7
1-[2-(hydroxymethyl)-4-methylphenyl]-2-methyl-2-propen-1-ol

: 188014-78-0
Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 78 percent / imidazole / CH₂Cl₂ / 21 °C

2: 97 percent / collidine / CH₂Cl₂ / 21 °C

3: 89 percent / PPTS / aq. ethanol / 21 °C

4: 89 percent / CH₂Cl₂ / 21 °C / Dess-Martin ox.

5: 86 percent / tetrahydrofuran / -78 °C

6: 97 percent / i-PrEt₂N / CH₂Cl₂

With 1H-imidazole; 2,3,5-trimethyl-pyridine; N,N-diethyl-N-isopropylamine; pyridinium p-toluenesulfonate; In tetrahydrofuran; ethanol; dichloromethane;
DOI:10.1016/S0040-4039(96)02459-8