N-benzylpyridinium hexafluorophosphate

Base Information

• Chemical Name: N-benzylpyridinium hexafluorophosphate
• CAS No.: 26872-08-2
• Molecular Formula: C₁₂H₁₂N*F₆P
• Molecular Weight: 315.198
• Mol file: 26872-08-2.mol

Synonyms:N-benzylpyridinium hexafluorophosphate

Chemical Property of N-benzylpyridinium hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-benzylpyridinium hexafluorophosphate

There total 6 articles about N-benzylpyridinium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

N-benzylpyridinium bromide (2589-31-3) → N-benzylpyridinium hexafluorophosphate (26872-08-2)

Guidance literature:

With potassium hexafluorophosphate; In water; at 20 ℃; for 24h;

DOI:10.1002/ejoc.201300595

Reference yield: 91.0%

pyridine (110-86-1) + C22H22N2O → 1-benzyl-3-methyl-1H-indazole (128364-67-0) + N-benzylpyridinium hexafluorophosphate (26872-08-2)

Guidance literature:

With 2-(1-piperidino) propiophenone; p-toluenesulfonyl chloride; In dichloromethane; at 0 ℃; for 1h; Inert atmosphere;

DOI:10.1039/c8cc00183a

Reference yield:

N-benzylpyridinium chloride (2876-13-3) → N-benzylpyridinium hexafluorophosphate (26872-08-2)

Guidance literature:

With silver(I) hexafluorophosphate; In acetone; at 20 ℃; for 18h; Inert atmosphere; Darkness;

DOI:10.1002/anie.200802745

upstream raw materials:

N-benzylpyridinium chloride

pyridine

benzyl bromide

N-benzylpyridinium bromide

Downstream raw materials:

(R)-(-)-coniine (S)-(+)-mandelic acid salt

1-benzyl-2-n-propylpiperidine

1-benzyl-1,2,3,6-tetrahydropyridine-2-carbonitrile

N-benzylpyridinium chloride

Refernces

• 1、 Vu, Van Ha,Jouanno, Laurie-Anne,Cheignon, Adele,Roisnel, Thierry,Dorcet, Vincent,Sinbandhit, Sourisak,Hurvois, Jean-Pierre. "Modified fry cyanation of a chiral pyridinium salt: Asymmetric syntheses of (-)-coniine and (-)-solenopsin A". . p. 5464 - 5474. Retrieved 2013/09/02.
• 2、 Barrell, Michael J.,Leigh, David A.,Lusby, Paul J.,Slawin, Alexandra M. Z.. "An ion-pair template for rotaxane formation and its exploitation in an orthogonal interaction anion-switchable molecular shuttle". supporting information; experimental part. p. 8036 - 8039. Retrieved 2009/04/13.