N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide

Base Information

Chemical Name:N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide
CAS No.:1307916-82-0
Molecular Formula:C₅₂H₅₂N₂O₆
Molecular Weight:800.995
Hs Code.:

Synonyms:N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide

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Chemical Property of N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide

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Technology Process of N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide

There total 5 articles about N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1307916-81-9
1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboxylic anhydride

: 27532-96-3
glycine tert-butyl ester hydrochloride

: 1307916-82-0
N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 100 ℃;
DOI:10.1039/c0cc05755j

Reference yield:

: 1,6-bis(4-tert-butylphenoxy)-9-[2-(bromide)ethynyl]-N-(2,5-di-tert-butylphenyl)-3,4-perylenedicarboximide

: 1307916-82-0
N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide

Guidance literature:: Multi-step reaction with 3 steps

1.1: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate / toluene / 100 °C

2.1: potassium hydroxide / tert-butyl alcohol / 3 h / Reflux

2.2: 20 °C

3.1: potassium carbonate / N,N-dimethyl-formamide / 100 °C

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; potassium hydroxide; sodium t-butanolate; In N,N-dimethyl-formamide; toluene; tert-butyl alcohol;
DOI:10.1039/c0cc05755j

Reference yield:

: 1307916-80-8
1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)-N-(2,5-di-tert-butylphenyl)perylene-3,4-dicarboximide

: 1307916-82-0
N-(tert-butoxycarbonylmethylene)-1-(N-pyrrolidino)-6,9-di(tert-butoxyphenoxy)perylene-3,4-dicarboximide

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium hydroxide / tert-butyl alcohol / 3 h / Reflux

1.2: 20 °C

2.1: potassium carbonate / N,N-dimethyl-formamide / 100 °C

With potassium carbonate; potassium hydroxide; In N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1039/c0cc05755j