2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Base Information

Chemical Name:2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate
CAS No.:355010-33-2
Molecular Formula:C₃₆H₇₀N₂O₉Si₄
Molecular Weight:787.302
Hs Code.:

Synonyms:2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Suppliers and Price of 2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

There total 4 articles about 2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

: 2916-68-9
2-(Trimethylsilyl)ethanol

: 355010-40-1
2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranosiduronic acid

: 355010-33-2
2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 12h;
DOI:10.1002/1099-0690(200106)2001:11<2129::AID-EJOC2129>3.0.CO;2-#

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 355010-33-2
2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Guidance literature:: Multi-step reaction with 2 steps

1: 457 mg / DMAP / pyridine / 48 h / 20 °C

2: 39 percent / DCC; DMAP / CH₂Cl₂ / 12 h / 20 °C

With dmap; dicyclohexyl-carbodiimide; In pyridine; dichloromethane;
DOI:10.1002/1099-0690(200106)2001:11<2129::AID-EJOC2129>3.0.CO;2-#

Reference yield:

: 191352-30-4
(2S,3S,4S,5R,6S)-2-(methoxycarbonyl)-6-(2-(methylamino)-4-nitrophenoxy)tetrahydro-2H-pyran-3,4,5-triyl triacetate

: 355010-33-2
2-(trimethylsilyl)ethyl [2-methylamino-4-nitrophenyl-2,3,4-tri-O-(tert-butyldimethylsilyl)-β-D-glucopyranoside]uronate

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / aq. NaOH / acetone / 0.08 h / 0 °C

2: 457 mg / DMAP / pyridine / 48 h / 20 °C

3: 39 percent / DCC; DMAP / CH₂Cl₂ / 12 h / 20 °C

With dmap; sodium hydroxide; dicyclohexyl-carbodiimide; In pyridine; dichloromethane; acetone;
DOI:10.1002/1099-0690(200106)2001:11<2129::AID-EJOC2129>3.0.CO;2-#